Copper (II) chloride dihydrate-catalyzed cascade reaction of β-anhydroicaritin with alcohol

被引：0
|
作者：
Huang, Chuting [1 ]
Zhao, Zhao [1 ]
Wang, Xianheng [1 ]
Liu, Huimin [1 ]
Wang, Yuhe [2 ]
Zhao, Changkuo [1 ]
机构：
[1] Zunyi Med Univ, Dept Med Chem, 6 Xue Fu West Rd, Zunyi 563003, Guizhou Provinc, Peoples R China
[2] Zunyi Med Univ, Affiliated Hosp, Dept Pharm, 139 Dalian Rd, Zunyi 563003, Guizhou Provinc, Peoples R China
来源：
TETRAHEDRON | 2025年 / 172卷
关键词：
beta-anhydroicaritin; Copper (II) chloride dihydrate; Alcoholysis; Cascade reaction; Hydrate; OXIDATION; QUERCETIN; ICARITIN;
D O I：
10.1016/j.tet.2025.134452
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Hydrate is a kind of unstable and uneasy prepared organic compounds. In this article, a cascade reaction of beta-anhydroicaritin with alcohols catalyzed by CuCl2 & sdot;2H2O to form hydrate has been successfully developed in good yields. Different reaction conditions, including molar ratios, solvents, temperature and times were optimized, and the mechanism was also investigated.
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页数：7
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