Copper (II) chloride dihydrate-catalyzed cascade reaction of β-anhydroicaritin with alcohol

被引：0

作者：

Huang, Chuting ^{[1
]}

Zhao, Zhao ^{[1
]}

Wang, Xianheng ^{[1
]}

Liu, Huimin ^{[1
]}

Wang, Yuhe ^{[2
]}

Zhao, Changkuo ^{[1
]}

机构：

[1] Zunyi Med Univ, Dept Med Chem, 6 Xue Fu West Rd, Zunyi 563003, Guizhou Provinc, Peoples R China

[2] Zunyi Med Univ, Affiliated Hosp, Dept Pharm, 139 Dalian Rd, Zunyi 563003, Guizhou Provinc, Peoples R China

来源：

TETRAHEDRON | 2025年 / 172卷

关键词：

beta-anhydroicaritin; Copper (II) chloride dihydrate; Alcoholysis; Cascade reaction; Hydrate; OXIDATION; QUERCETIN; ICARITIN;

D O I：

10.1016/j.tet.2025.134452

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydrate is a kind of unstable and uneasy prepared organic compounds. In this article, a cascade reaction of beta-anhydroicaritin with alcohols catalyzed by CuCl2 & sdot;2H2O to form hydrate has been successfully developed in good yields. Different reaction conditions, including molar ratios, solvents, temperature and times were optimized, and the mechanism was also investigated.

引用

页数：7

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