Low-temperature synthesis of nanocrystalline titanium nitride via a benzene-thermal route

被引：0

作者：

Hu, Junqing ^{[1
]}

Lu, Qingyi ^{[1
]}

Tang, Kaibin ^{[1
]}

Yu, Shuhong ^{[1
]}

Qian, Yitai ^{[1
]}

Zhou, Guien ^{[1
]}

Liu, Xianming ^{[1
]}

机构：

[1] Dept. of Chem. and Struct. Res. Lab., Univ. of Sci. and Technol. of China, Hefei 230026, China

来源：

| 1600年 / American Ceramic Soc, Westerville卷 / 83期

关键词：

Experimental; (EXP);

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A benzene-thermal reaction of TiCl4 and NaN3 at 350°-380°C was unducted for the preparation of nanocrystalline TiN. Powder X-ray diffractometry patterns indicated that the powder was cubic-phase TiN with a lattice constant a = 4.23656 angstrom. Transmission electron microscopy images showed the TiN powder consisted of uniform spherical particles with an average diameter of 50 nm. The binding energies of Ti 2p3/2 and N 1s core levels at the positions of 454.85 and 397.1 eV, respectively, and the Ti:N atomic ratio of 1.08:1.00 were detected by X-ray photoelectron spectra. A possible formation mechanism of TiN was proposed.

引用

共 50 条

[41] Low-temperature synthesis of nanocrystalline TiC
Chernikova, E.S.
Timofeeva, I.I.
Uvarova, I.V.
Bykov, A.I.
Skorokhod, V.V.
Smirnov, V.P.
Xiaoxing Weixing Jisuanji Xitong/Mini-Micro Systems, 1998, 19 (12): : 32 - 38
[42] Low temperature synthesis of nanocrystalline titanium nitride from a single-source precursor of titanium and nitrogen
Wu, Meining
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 486 (1-2) : 223 - 226
[43] Low temperature synthesis of nanocrystalline titanium nitride from a single-source precursor of titanium and nitrogen
Wu, Meining
Journal of Alloys and Compounds, 2009, 486 (1-2): : 223 - 226
[44] Low temperature synthesis of nanocrystalline tantalum nitride
Zhang, Kailong
Wu, Luanhui
Zhang, Chao
Yang, Qidong
Qian, Wei
Hu, Guang
Hu, Weiwei
Kong, Yazhou
Wang, Liangbiao
Li, Gaoran
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2023, 131 (06) : 178 - 180
[45] Low-temperature synthesis and thermal expansion of nanocrystalline monoclinic zirconolite ceramics
Patil, Bhimarao M.
Wadhawa, Gurumeet C.
Chaskar, Atul C.
Walke, Pravin S.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2023, 148 (15) : 7591 - 7596
[46] Low-temperature synthesis and thermal expansion of nanocrystalline monoclinic zirconolite ceramics
Bhimarao M. Patil
Gurumeet C. Wadhawa
Atul C. Chaskar
Pravin S. Walke
Journal of Thermal Analysis and Calorimetry, 2023, 148 : 7591 - 7596
[47] Synthesis of uniform titanium nitride nanocrystalline powders via a reduction-hydrogenation-dehydrogenation-nitridation route
Guo, QX
Xie, Y
Wang, XJ
Lv, SC
Hou, T
Bai, C
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2005, 88 (01) : 249 - 251
[48] LOW-TEMPERATURE CREEP OF NANOCRYSTALLINE TITANIUM(IV) OXIDE
HAHN, H
AVERBACK, RS
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1991, 74 (11) : 2918 - 2921
[49] Elastic properties of porous silicon nitride fabricated via a low-temperature processing route
Kota, Navya
Jana, Prasanta
Roy, Siddhartha
CERAMICS INTERNATIONAL, 2023, 49 (04) : 7066 - 7079
[50] LOW-TEMPERATURE THERMAL CONDUCTIVITY OF URANIUM NITRIDE
RADOSEVICH, LG
WILLIAMS, WS
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1969, 52 (09) : 514 - +

← 1 2 3 4 5 →