Improvement of corrosion resistance and electrical conductivity of a Cr-C coated heat-assisted forming stainless steel bipolar plate for proton exchange membrane fuel cell

被引:4
|
作者
Leng, Yu [1 ,2 ]
Yang, Daijun [3 ,4 ]
Min, Junying [5 ]
Lv, Xinyu [1 ,2 ]
Yang, Jian [1 ,2 ]
Qian, Junfeng [1 ,2 ]
Ming, Pingwen [3 ,4 ]
Zhang, Cunman [3 ,4 ]
机构
[1] Changzhou Univ, Sch Petrochem Engn, 21 Gehu Rd, Changzhou 213164, Peoples R China
[2] Changzhou Univ, Changzhou Univ Branch, United Chem React Engn Res Inst, 21 Gehu Rd, Changzhou 213164, Peoples R China
[3] Tongji Univ, Sch Automot Studies, 4800 Caoangong Rd, Shanghai 200092, Peoples R China
[4] Tongji Univ, New Energy Automot Engn Ctr, 4800 Caoangong Rd, Shanghai 200029, Peoples R China
[5] Tongji Univ, Sch Mech Engn, 4800 Caoangong Rd, Shanghai 200092, Peoples R China
关键词
Heat-assisted forming; Cr-C coating; Corrosion resistance; Electrical conductivity; Bipolar plate; HIGH-TEMPERATURE; CONTACT RESISTANCE; OXIDE-FILMS; ALLOY FOIL; EVOLUTION; OXIDATION; 304-STAINLESS-STEEL; MECHANISM; COATINGS; 316L;
D O I
10.1016/j.ijhydene.2024.05.194
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Heat-assisted forming is gaining increasing attention for its potential in improving the formability and quality of metallic bipolar plate (BPP) of proton exchange membrane fuel cell (PEMFC). However, the effects of heatassisted forming and the subsequent coating process on corrosion resistance and electrical conductivity of stainless steel BPP still remain unclear. This work proposes a way to improve simultaneously the corrosion resistance and electrical conductivity of heat-assisted forming stainless steel BPP by depositing a Cr-C coating directly on its surface without removing the oxide layer using the magnetron sputtering method. Potentiodynamic tests indicate that self-corrosion current density and corrosion current density at 1.0 V (vs. Ag/AgCl) of the Cr-C coated heat-assisted forming SS316L BPP prepared under 900 degrees C for 10 min are 0.021-0.040 mu A cm-2 and 77.54 mu A cm-2, respectively, both of which are smaller than those of coated SS316L BPP formed under room temperature. In addition, the contact resistance is close to that of the gold-plated copper plate under the same pressure. The corrosion resistant intermediate oxide layer and conductive network formed between Cr-C coating and metal substrate through defects of oxide layer may be the main reason for improvement of its corrosion resistance and electrical conductivity, respectively.
引用
收藏
页码:183 / 194
页数:12
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