Improvement of corrosion resistance and electrical conductivity of a Cr-C coated heat-assisted forming stainless steel bipolar plate for proton exchange membrane fuel cell

被引:4
|
作者
Leng, Yu [1 ,2 ]
Yang, Daijun [3 ,4 ]
Min, Junying [5 ]
Lv, Xinyu [1 ,2 ]
Yang, Jian [1 ,2 ]
Qian, Junfeng [1 ,2 ]
Ming, Pingwen [3 ,4 ]
Zhang, Cunman [3 ,4 ]
机构
[1] Changzhou Univ, Sch Petrochem Engn, 21 Gehu Rd, Changzhou 213164, Peoples R China
[2] Changzhou Univ, Changzhou Univ Branch, United Chem React Engn Res Inst, 21 Gehu Rd, Changzhou 213164, Peoples R China
[3] Tongji Univ, Sch Automot Studies, 4800 Caoangong Rd, Shanghai 200092, Peoples R China
[4] Tongji Univ, New Energy Automot Engn Ctr, 4800 Caoangong Rd, Shanghai 200029, Peoples R China
[5] Tongji Univ, Sch Mech Engn, 4800 Caoangong Rd, Shanghai 200092, Peoples R China
关键词
Heat-assisted forming; Cr-C coating; Corrosion resistance; Electrical conductivity; Bipolar plate; HIGH-TEMPERATURE; CONTACT RESISTANCE; OXIDE-FILMS; ALLOY FOIL; EVOLUTION; OXIDATION; 304-STAINLESS-STEEL; MECHANISM; COATINGS; 316L;
D O I
10.1016/j.ijhydene.2024.05.194
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Heat-assisted forming is gaining increasing attention for its potential in improving the formability and quality of metallic bipolar plate (BPP) of proton exchange membrane fuel cell (PEMFC). However, the effects of heatassisted forming and the subsequent coating process on corrosion resistance and electrical conductivity of stainless steel BPP still remain unclear. This work proposes a way to improve simultaneously the corrosion resistance and electrical conductivity of heat-assisted forming stainless steel BPP by depositing a Cr-C coating directly on its surface without removing the oxide layer using the magnetron sputtering method. Potentiodynamic tests indicate that self-corrosion current density and corrosion current density at 1.0 V (vs. Ag/AgCl) of the Cr-C coated heat-assisted forming SS316L BPP prepared under 900 degrees C for 10 min are 0.021-0.040 mu A cm-2 and 77.54 mu A cm-2, respectively, both of which are smaller than those of coated SS316L BPP formed under room temperature. In addition, the contact resistance is close to that of the gold-plated copper plate under the same pressure. The corrosion resistant intermediate oxide layer and conductive network formed between Cr-C coating and metal substrate through defects of oxide layer may be the main reason for improvement of its corrosion resistance and electrical conductivity, respectively.
引用
收藏
页码:183 / 194
页数:12
相关论文
共 50 条
  • [31] Stainless steel bipolar plate coated with carbon nanotube (CNT)/polytetrafluoroethylene (PTFE) composite film for proton exchange membrane fuel cell (PEMFC)
    Show, Yoshiyuki
    Takahashi, Kenta
    JOURNAL OF POWER SOURCES, 2009, 190 (02) : 322 - 325
  • [32] Corrosion behavior of a ZrCN coated Ti alloy with potential application as a bipolar plate for proton exchange membrane fuel cell
    Xu, Jiang
    Huang, Hao Jie
    Li, ZhengYang
    Xu, Song
    Tao, Hongliang
    Munroe, Paul
    Xie, Zong-Han
    JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 663 : 718 - 730
  • [33] Chromium interlayer amorphous carbon film for 304 stainless steel bipolar plate of proton exchange membrane fuel cell
    Wu Mingge
    Lu Congda
    Hong Tao
    Chen Guohai
    Wen Donghui
    SURFACE & COATINGS TECHNOLOGY, 2016, 307 : 374 - 381
  • [34] Performance of Tantalum Modified 316L Stainless Steel Bipolar Plate for Proton Exchange Membrane Fuel Cell
    Li, T.
    Zhang, P. C.
    Liu, K.
    Xu, S.
    Han, Y. T.
    Shi, J. F.
    Sun, J. C.
    FUEL CELLS, 2019, 19 (06) : 724 - 730
  • [35] The influence of different heat treatment temperatures on forming property of bipolar plate for proton-exchange membrane fuel cell
    Wang, Yun
    Wu, Jun-Feng
    Xu, Zhen-Ying
    Chen, Wan-Rong
    Yin, Bi-Feng
    Ding, Sheng
    Gongneng Cailiao/Journal of Functional Materials, 2014, 45 (08): : 08052 - 08055
  • [36] Nanocrystalline TaCN coated titanium bipolar plate dedicated to proton exchange membrane fuel cell
    Chen, Yuhao
    Xu, Jiang
    Xie, Zong-Han
    Munroe, Paul
    CERAMICS INTERNATIONAL, 2022, 48 (13) : 19217 - 19231
  • [37] Carbon-based films coated 316L stainless steel as bipolar plate for proton exchange membrane fuel cells
    Fu, Yu
    Lin, Guoqiang
    Hou, Ming
    Wu, Bo
    Shao, Zhigang
    Yi, Baolian
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (01) : 405 - 409
  • [38] Role of oxide layer on corrosion resistance and surface conductivity of titanium bipolar plates for proton exchange membrane fuel cell
    Chen, Bo
    Ge, Biao
    Zhang, Xianglu
    Yang, Daijun
    Yang, Peiyong
    Lu, Wei
    Min, Junying
    Ming, Pingwen
    Zhang, Cunman
    JOURNAL OF POWER SOURCES, 2024, 624
  • [39] Characterization of Uncoated Stainless Steel as Proton Exchange Membrane Fuel Cell Bipolar Plates Material
    Caque, N.
    Paris, M.
    Chatenet, M.
    Rossinot, E.
    Bousquet, R.
    Claude, E.
    FUEL CELLS, 2012, 12 (02) : 248 - 255
  • [40] Enhanced corrosion resistance of LaBC film for bipolar plate coatings in proton exchange membrane fuel cells
    Chen, Li
    Lv, Jianxiang
    Liu, Ruixuan
    Yang, Panfeng
    Zhang, Bin
    DIAMOND AND RELATED MATERIALS, 2024, 148