Improvement of corrosion resistance and electrical conductivity of a Cr-C coated heat-assisted forming stainless steel bipolar plate for proton exchange membrane fuel cell

被引:4
|
作者
Leng, Yu [1 ,2 ]
Yang, Daijun [3 ,4 ]
Min, Junying [5 ]
Lv, Xinyu [1 ,2 ]
Yang, Jian [1 ,2 ]
Qian, Junfeng [1 ,2 ]
Ming, Pingwen [3 ,4 ]
Zhang, Cunman [3 ,4 ]
机构
[1] Changzhou Univ, Sch Petrochem Engn, 21 Gehu Rd, Changzhou 213164, Peoples R China
[2] Changzhou Univ, Changzhou Univ Branch, United Chem React Engn Res Inst, 21 Gehu Rd, Changzhou 213164, Peoples R China
[3] Tongji Univ, Sch Automot Studies, 4800 Caoangong Rd, Shanghai 200092, Peoples R China
[4] Tongji Univ, New Energy Automot Engn Ctr, 4800 Caoangong Rd, Shanghai 200029, Peoples R China
[5] Tongji Univ, Sch Mech Engn, 4800 Caoangong Rd, Shanghai 200092, Peoples R China
关键词
Heat-assisted forming; Cr-C coating; Corrosion resistance; Electrical conductivity; Bipolar plate; HIGH-TEMPERATURE; CONTACT RESISTANCE; OXIDE-FILMS; ALLOY FOIL; EVOLUTION; OXIDATION; 304-STAINLESS-STEEL; MECHANISM; COATINGS; 316L;
D O I
10.1016/j.ijhydene.2024.05.194
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Heat-assisted forming is gaining increasing attention for its potential in improving the formability and quality of metallic bipolar plate (BPP) of proton exchange membrane fuel cell (PEMFC). However, the effects of heatassisted forming and the subsequent coating process on corrosion resistance and electrical conductivity of stainless steel BPP still remain unclear. This work proposes a way to improve simultaneously the corrosion resistance and electrical conductivity of heat-assisted forming stainless steel BPP by depositing a Cr-C coating directly on its surface without removing the oxide layer using the magnetron sputtering method. Potentiodynamic tests indicate that self-corrosion current density and corrosion current density at 1.0 V (vs. Ag/AgCl) of the Cr-C coated heat-assisted forming SS316L BPP prepared under 900 degrees C for 10 min are 0.021-0.040 mu A cm-2 and 77.54 mu A cm-2, respectively, both of which are smaller than those of coated SS316L BPP formed under room temperature. In addition, the contact resistance is close to that of the gold-plated copper plate under the same pressure. The corrosion resistant intermediate oxide layer and conductive network formed between Cr-C coating and metal substrate through defects of oxide layer may be the main reason for improvement of its corrosion resistance and electrical conductivity, respectively.
引用
收藏
页码:183 / 194
页数:12
相关论文
共 50 条
  • [21] Corrosion resistance and electrical conductivity of polyaniline film/stainless steel composite bipolar plate
    Zhou, Wan-Qiu
    Yang, Jia-Yu
    Liu, Xiao-An
    Jiang, Wen-Yin
    Xin, Shi-Gang
    Kang, Yan-Hong
    Surface Technology, 2019, 48 (12): : 320 - 327
  • [22] Investigation of evolution of γ N phase and its effect on conductivity and corrosion resistance of plasma-nitrided 316 L stainless steel bipolar plate for proton exchange membrane fuel cell
    Liu, Chunpeng
    Li, Chuanwei
    Ye, Zhenhua
    Suo, Zhongyuan
    Jiang, Feng
    Gu, Jianfeng
    SURFACE TOPOGRAPHY-METROLOGY AND PROPERTIES, 2024, 12 (02)
  • [23] Optimized Cr-nitride film on 316L stainless steel as proton exchange membrane fuel cell bipolar plate
    Fu, Yu
    Lin, Guoqiang
    Hou, Ming
    Wu, Bo
    Li, Hongkai
    Hao, Lixing
    Shao, Zhigang
    Yi, Baolian
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (01) : 453 - 458
  • [24] A comparative study of corrosion resistance evaluation of bipolar plate materials for proton exchange membrane fuel cell
    Leng, Yu
    Yang, Daijun
    Ming, Pingwen
    Zhang, Cunman
    ETRANSPORTATION, 2021, 10
  • [25] Molybdenum nitride modified AISI 304 stainless steel bipolar plate for proton exchange membrane fuel cell
    Wang, Lixia
    Sun, Juncai
    Li, Pengbin
    Sun, Jing
    Lv, Ying
    Jing, Bo
    Li, Song
    Ji, Shijun
    Wen, Zhongsheng
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (07) : 5876 - 5883
  • [26] NbC/Nb Film-Modified Stainless Steel Bipolar Plate for Proton Exchange Membrane Fuel Cell
    Deng, Hao
    Liu, Guoqing
    Du, Wei
    Sun, Yi
    Deng, Chengwei
    Li, Bing
    CORROSION, 2022, 78 (09) : 876 - 884
  • [27] Ag-polytetrafluoroethylene composite coating on stainless steel as bipolar plate of proton exchange membrane fuel cell
    Fu, Yu
    Hou, Ming
    Xu, Hongfeng
    Hou, Zhongjun
    Ming, Pingwen
    Shao, Zhigang
    Yi, Baolian
    JOURNAL OF POWER SOURCES, 2008, 182 (02) : 580 - 584
  • [28] Niobium nitride modified AISI 304 stainless steel bipolar plate for proton exchange membrane fuel cell
    Wang, Lixia
    Sun, Juncai
    Sun, Jing
    Lv, Ying
    Li, Song
    Ji, Shijun
    Wen, Zhongsheng
    JOURNAL OF POWER SOURCES, 2012, 199 : 195 - 200
  • [29] Coated stainless steel as bipolar plate material for anion exchange membrane fuel cells (AEMFCs)
    Proch, Sebastian
    Stenstrom, Mikael
    Eriksson, Lennart
    Andersson, Jan
    Sjoblom, Gustaf
    Jansson, Anna
    Westlinder, Jorgen
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2020, 45 (02) : 1313 - 1324
  • [30] Improved anticorrosion properties and electrical conductivity of 316L stainless steel as bipolar plate for proton exchange membrane fuel cell by lower temperature chromizing treatment
    Yang, Lijun
    Yu, Haijun
    Jiang, Lijun
    Zhu, Lei
    Jian, Xuyu
    Wang, Zhong
    JOURNAL OF POWER SOURCES, 2010, 195 (09) : 2810 - 2814