ELECTROCHEMICAL INVESTIGATIONS OF HIGH-SPIN (10,20-DIARYLETIOPORPHYRINATO-II) IRON(III) COMPLEXES

被引：0
|
作者：
KIJIMA, M
AKIMOTO, K
SAKAWAKI, A
SATO, T
机构：
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 01期
关键词：
D O I：
10.1246/bcsj.65.23
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The redox behaviors of high-spin (10,20-diaryletioporphyrinato II) iron(III) complexes were investigated by cyclic voltammetry in both anodic and cathodic regions in dichloromethane. Whether the redox waves are due to a porphyrin-ring-centered reaction or a metal-centered reaction was examined in terms of the spectroelectrochemical results and Hammett reaction constants.
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页码：23 / 28
页数：6
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