ELECTROCHEMICAL INVESTIGATIONS OF HIGH-SPIN (10,20-DIARYLETIOPORPHYRINATO-II) IRON(III) COMPLEXES

被引：0
|
作者：
KIJIMA, M
AKIMOTO, K
SAKAWAKI, A
SATO, T
机构：
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 01期
关键词：
D O I：
10.1246/bcsj.65.23
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The redox behaviors of high-spin (10,20-diaryletioporphyrinato II) iron(III) complexes were investigated by cyclic voltammetry in both anodic and cathodic regions in dichloromethane. Whether the redox waves are due to a porphyrin-ring-centered reaction or a metal-centered reaction was examined in terms of the spectroelectrochemical results and Hammett reaction constants.
引用
收藏
页码：23 / 28
页数：6
相关论文
共 50 条
  • [11] SYNTHESIS, PROPERTIES AND STRUCTURES OF NEW HIGH-SPIN LOW-SPIN COMPLEXES OF IRON(III)
    BUTCHER, RJ
    GREEN, R
    REIFF, WM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 : 119 - INOR
  • [12] Spin Crossover during β-Hydride Elimination in High-Spin Iron(II)- and Cobalt(II)-Alkyl Complexes
    Bellows, Sarina M.
    Cundari, Thomas R.
    Holland, Patrick L.
    ORGANOMETALLICS, 2013, 32 (17) : 4741 - 4751
  • [13] Structural, spectroscopic, and electrochemical properties of a series of high-spin thiolatonickel(II) complexes
    Cho, Jaeheung
    Yap, Glenn P. A.
    Riordan, Charles G.
    INORGANIC CHEMISTRY, 2007, 46 (26) : 11308 - 11315
  • [14] MAGNETIC PROPERTIES OF SOME DISTORTED OCTAHEDRAL HIGH-SPIN IRON(II) COMPLEXES
    LONG, GJ
    BAKER, WA
    JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (18): : 2956 - &
  • [15] Reversible Addition of CO to Coordinatively Unsaturated High-Spin Iron(II) Complexes
    Holzhacker, Christian
    Standfest-Hauser, Christina M.
    Puchberger, Michael
    Mereiter, Kurt
    Veiros, Luis F.
    Calhorda, Maria Jose
    Carvalho, Maria Deus
    Ferreira, Liliana P.
    Godinho, Margarida
    Hartl, Frantisek
    Kirchner, Karl
    ORGANOMETALLICS, 2011, 30 (24) : 6587 - 6601
  • [16] All square for high-spin iron(II)
    Patrick L. Holland
    Nature Chemistry, 2011, 3 : 507 - 508
  • [17] On the nature of metastable high-spin states formed during spin transitions in iron(II) complexes
    Varnek, VA
    JOURNAL OF STRUCTURAL CHEMISTRY, 1996, 37 (03) : 514 - 516
  • [18] IRON(0) ARENA AND IRON(II) HYDRIDE COMPLEXES FROM THE HYDROGENATION OR THERMOLYSIS OF HIGH-SPIN IRON(II) ALKYLS
    HERMES, AR
    WARREN, TH
    GIROLAMI, GS
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (02): : 301 - 305
  • [19] Iron(II) High-Spin and Low-Spin Complexes from Pentaisopropylcyclopentadienyliron(II) Bis(trimethylsilyl)amide
    Gross, Oliver A.
    Lauk, Sergej
    Mueller, Carsten
    Gidt, Wjatscheslaw
    Sun, Yu
    Demeshko, Serhiy
    Meyer, Franc
    Sitzmann, Helmut
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (30) : 3635 - 3643
  • [20] Deprotonation of low-spin mononuclear iron(III)-hydroperoxide complexes give transient blue species assigned to high-spin iron(III)-peroxide complexes
    Jensen, KB
    McKenzie, CJ
    Nielsen, LP
    JOURNAL OF INORGANIC BIOCHEMISTRY, 1999, 74 (1-4) : 229 - 229
12345