EXO-SELECTIVE ACCELERATION OF AN INTERMOLECULAR DIELS-ALDER REACTION BY A TRIMERIC PORPHYRIN HOST

被引：133

作者：

WALTER, CJ ^{[1
]}

ANDERSON, HL ^{[1
]}

SANDERS, JKM ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CTR MOLEC RECOGNIT,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 05期

关键词：

D O I：

10.1039/c39930000458

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A bimolecular Diels-Alder reaction is accelerated substantially and stereoselectively by binding diene and dienophile within the cavity of a cyclic metalloporphyrin trimer.

引用

页码：458 / 460

页数：3

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