EXO-SELECTIVE ACCELERATION OF AN INTERMOLECULAR DIELS-ALDER REACTION BY A TRIMERIC PORPHYRIN HOST

被引：133
|
作者：
WALTER, CJ [1 ]
ANDERSON, HL [1 ]
SANDERS, JKM [1 ]
机构：
[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CTR MOLEC RECOGNIT,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 05期
关键词：
D O I：
10.1039/c39930000458
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A bimolecular Diels-Alder reaction is accelerated substantially and stereoselectively by binding diene and dienophile within the cavity of a cyclic metalloporphyrin trimer.
引用
收藏
页码：458 / 460
页数：3
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