EXO-SELECTIVE ACCELERATION OF AN INTERMOLECULAR DIELS-ALDER REACTION BY A TRIMERIC PORPHYRIN HOST

被引：133
|
作者：
WALTER, CJ [1 ]
ANDERSON, HL [1 ]
SANDERS, JKM [1 ]
机构：
[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CTR MOLEC RECOGNIT,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 05期
关键词：
D O I：
10.1039/c39930000458
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A bimolecular Diels-Alder reaction is accelerated substantially and stereoselectively by binding diene and dienophile within the cavity of a cyclic metalloporphyrin trimer.
引用
收藏
页码：458 / 460
页数：3
相关论文
共 50 条
  • [1] Exo-Selective and Enantioselective Photoenolization/Diels-Alder Reaction
    Hou, Min
    Xu, Mengmeng
    Yang, Baochao
    He, Haibing
    Gao, Shuanhu
    ORGANIC LETTERS, 2021, 23 (19) : 7487 - 7491
  • [2] Exo-Selective Diels-Alder Reactions
    Li, Yuan-He
    Chen, Jia-Hua
    Yang, Zhen
    CHEMISTRY-A EUROPEAN JOURNAL, 2024, 30 (17)
  • [3] Exo-selective asymmetric Diels-Alder reaction of acrylate ester
    Kawamura, M
    Kudo, K
    CHIRALITY, 2002, 14 (09) : 727 - 730
  • [4] PHOTOINDUCED EXO-SELECTIVE DIELS-ALDER REACTIONS
    PANDEY, B
    DALVI, PV
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (11): : 1612 - 1613
  • [5] AN APPROACH TO QUASSIMARIN BASED ON AN EXO-SELECTIVE INTRAMOLECULAR DIELS-ALDER REACTION
    SCHLESSINGER, RH
    WONG, JW
    POSS, MA
    SPRINGER, JP
    JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (20): : 3950 - 3951
  • [6] exo-selective asymmetric Diels-Alder reaction catalyzed by diamine salts as organocatalysts
    Kano, Taichi
    Tanaka, Youhei
    Maruoka, Keiji
    CHEMISTRY-AN ASIAN JOURNAL, 2007, 2 (09) : 1161 - 1165
  • [7] exo-Selective asymmetric Diels-Alder reaction catalyzed by diamine salts as organocatalysts
    Kano, Taichi
    Tanaka, Youhei
    Maruoka, Keiji
    ORGANIC LETTERS, 2006, 8 (13) : 2687 - 2689
  • [8] Enzymatic Activity Catalysing Exo-selective Diels-Alder Reaction in Solanapyrone Biosynthesis
    Oikawa, H.
    Katayama, K.
    Suzuki, Y.
    Ichihara, A.
    Journal of Automatic Chemistry, 1994, 162 (53):
  • [9] Diarylprolinol silyl ether as catalyst of an exo-selective, enantioselective Diels-Alder reaction
    Gotoh, Hiroaki
    Hayashi, Yujiro
    ORGANIC LETTERS, 2007, 9 (15) : 2859 - 2862
  • [10] EXO-SELECTIVE DIELS-ALDER REACTION-BASED ON A MOLECULAR RECOGNITION APPROACH
    MARUOKA, K
    IMOTO, H
    YAMAMOTO, H
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (26) : 12115 - 12116
12345