ONE-DIMENSIONAL AND 2-DIMENSIONAL FOURIER-TRANSFORM SPECTROSCOPY IN THE MICROWAVE AND RADIOFREQUENCY RANGE OF TRIFLUOROMETHANE IN THE VIBRATIONAL-STATE UPSILON-6=1

被引：6

作者：

HARDER, H

NICOLAISEN, HW

DREIZLER, H

MADER, H

机构：

[1] Institut für Physikalische Chemie, Abteilung Chemische Physik, Universität Kiel, D-24098 Kiel

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 214卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(93)85632-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

For trifluoromethane, CF3H, A1-A2 splittngs with KBAR=\k-l\=3 in the degenerate vibrational state nu6=1 have been determined using two-dimensional radiofrequency-microwave double resonance Fourier transform spectroscopy. The observation of direct l-type resonance transitions with KBAR=3 has been extended to lower J values by means of microwave Fourier transform spectroscopy. The analysis yielded improved values for the rotational constant C6, for the DELTAl= 0, DELTAk = +/- 6 interaction constant w6 and enabled the determination of a J dependence of the DELTAl= +/- 2, DELTAk = -/+ 4 t-type interaction constant.

引用

页码：265 / 270

页数：6

共 39 条

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BACALOGLU, R
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ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 205 : 156 - CELL
[33] SOLUTION STRUCTURE OF [(TRIPHOS-STAR)RHH2(AUPPH3)3][PF6]2 DEDUCED BY ONE-DIMENSIONAL AND 2-DIMENSIONAL H-1(P-31) AND H-1(RH-103) DOUBLE-RESONANCE TECHNIQUES
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MAGNETIC RESONANCE IN CHEMISTRY, 1991, 29 : S73 - S79
[34] PENDANT-CAPPED PORPHYRINS .2. STRUCTURAL-ANALYSIS AND DYNAMICS OF THE BIPHENYL PENDANT-CAPPED PORPHYRIN MODEL OF CATALASE AND ITS FE(III) COMPLEX BY ONE-DIMENSIONAL AND 2-DIMENSIONAL H-1-NMR SPECTROSCOPY AND DISTANCE GEOMETRY MOLECULAR MODELING REFINEMENT
BLASKO, A
GARCIA, B
BRUICE, TC
JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (21): : 5738 - 5747
[35] SYNTHESIS OF AMPHIPHILIC METAL ORGANICS USING P-MONOTHIOHYDROQUINOLATE, AN AMBIDENTATE LIGAND THAT BEARS A HARD AND A SOFT DONOR - ONE-DIMENSIONAL AND 2-DIMENSIONAL SOLID-STATE STRUCTURES OF FE-2(CO)(6)(MU-SC6H4-4-OH)(2)CENTER-DOT-NSOLV (SOLV=C6H6, N=1, SOLV=HSC6N4-4-OH, N=2)
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INORGANIC CHEMISTRY, 1995, 34 (22) : 5429 - 5436
[36] SPIN-DENSITY WAVE GROUND-STATE IN THE ONE-DIMENSIONAL CONDUCTOR (TMTSF)2PF6 - MICROSCOPIC EVIDENCE FROM SE-77 AND H-1-NMR EXPERIMENTS
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[37] SPIN-DENSITY WAVE GROUND STATE IN THE ONE-DIMENSIONAL CONDUCTOR (TMTSF)2PF6: MICROSCOPIC EVIDENCE FROM 77Se AND 1H NMR EXPERIMENTS.
Andrieux, A.
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Journal de physique. Lettres, 1981, 42 (04): : 87 - 90
[38] LOCAL ORDER, CONFORMATION, AND INTERACTION IN NEMATIC 4-(N-PENTYLOXY)-4'-CYANOBIPHENYL AND ITS ONE-TO-ONE MIXTURE WITH 1-(4'-CYANOPHENYL)-4-PROPYLCYCLOHEXANE - A STUDY BY STATE-CORRELATED H-1 2-DIMENSIONAL NMR-SPECTROSCOPY
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JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (23): : 9523 - 9529
[39] TRANSITION-METAL COMPLEXES WITH THE NOVEL POLY(1,2,4-TRIAZOLYL)BORATE LIGANDS [HNB(C2H2N3)(4-N)](- (N=1 AND 2) - SYNTHESIS AND CHARACTERIZATION OF METAL-COMPLEXES OF DIHYDROBIS(1,2,4-TRIAZOLYL)BORATE AS ONE-DIMENSIONAL OR 2-DIMENSIONAL COORDINATION POLYMERS WITH 6-MEMBERED RING WATER SUBSTRUCTURES AND THE STRUCTURE OF 2-DIMENSIONAL LIQUID AND SOLID WATER AS ORGANIZED IN THE INTERCALATE [NI(HB(C2H2N3)(3))(2)]CENTER-DOT-6H2O (X-RAY STUDIES AT 293-K AND 160-K)
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