ONE-DIMENSIONAL AND 2-DIMENSIONAL FOURIER-TRANSFORM SPECTROSCOPY IN THE MICROWAVE AND RADIOFREQUENCY RANGE OF TRIFLUOROMETHANE IN THE VIBRATIONAL-STATE UPSILON-6=1

被引：6

作者：

HARDER, H

NICOLAISEN, HW

DREIZLER, H

MADER, H

机构：

[1] Institut für Physikalische Chemie, Abteilung Chemische Physik, Universität Kiel, D-24098 Kiel

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 214卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(93)85632-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

For trifluoromethane, CF3H, A1-A2 splittngs with KBAR=\k-l\=3 in the degenerate vibrational state nu6=1 have been determined using two-dimensional radiofrequency-microwave double resonance Fourier transform spectroscopy. The observation of direct l-type resonance transitions with KBAR=3 has been extended to lower J values by means of microwave Fourier transform spectroscopy. The analysis yielded improved values for the rotational constant C6, for the DELTAl= 0, DELTAk = +/- 6 interaction constant w6 and enabled the determination of a J dependence of the DELTAl= +/- 2, DELTAk = -/+ 4 t-type interaction constant.

引用

页码：265 / 270

页数：6

共 39 条

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[22] THE ROTATIONAL SPECTRUM AND DIPOLE-MOMENT OF 1,1,1,2,3,3,3-HEPTAFLUOROPROPANE IN ITS VIBRATIONAL GROUND-STATE AS OBSERVED BY PULSED MOLECULAR-BEAM MICROWAVE FOURIER-TRANSFORM SPECTROSCOPY
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JOURNAL OF MOLECULAR SPECTROSCOPY, 1991, 146 (02) : 402 - 408
[23] INVESTIGATION OF PROFLAVINE INTERACTION WITH DEOXYTETRARIBONUCLEOSIDE TRIPHOSPHATE 5'-D(APGPCPT) IN AQUEOUS-SOLUTION BY THE METHOD OF ONE-DIMENSIONAL AND 2-DIMENSIONAL H-1-NMR SPECTROSCOPY
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BIOFIZIKA, 1992, 37 (01): : 23 - 33
[24] THE INVESTIGATION OF THE SOLUTION STRUCTURE OF DUPLEX D(PTGTTTGGC) . D(CCAAAC)A BY MEANS OF ONE-DIMENSIONAL AND 2-DIMENSIONAL H-1-NMR SPECTROSCOPY AND BY RESTRAINED MOLECULAR MECHANICS
BICHENCOVA, EV
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KUTYAVIN, IV
LEBEDEV, AV
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BIOORGANICHESKAYA KHIMIYA, 1990, 16 (09): : 1236 - 1258
[25] STRUCTURE OF PHENOLIC ISOMERS OF 2-NITROFLUORANTHENE AND 3-NITROFLUORANTHENE STUDIED BY ONE-DIMENSIONAL AND 2-DIMENSIONAL H-1-NMR SPECTROSCOPY - COMPARATIVE-ANALYSIS OF MUTAGENICITY
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CHEMICAL RESEARCH IN TOXICOLOGY, 1994, 7 (03) : 352 - 357
[26] STEREOCHEMICAL STRUCTURES OF SOME POLYACRYLATES STUDIED BY ONE-DIMENSIONAL AND 2-DIMENSIONAL C-13-H-1 NMR-SPECTROSCOPY (VOL 35, PG 3389, 1994)
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POLYMER, 1994, 35 (22) : 4928 - 4928
[27] STUDIES OF THE NEUTRAL TRISACCHARIDES OF GOAT (CAPRA-HIRCUS) COLOSTRUM AND OF THE ONE-DIMENSIONAL AND 2-DIMENSIONAL H-1 AND C-13 NMR-SPECTRA OF 6'-N-ACETYLGLUCOSAMINYLLACTOSE
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CARBOHYDRATE RESEARCH, 1994, 262 (02) : 173 - 184
[28] ONE-DIMENSIONAL AND 2-DIMENSIONAL S=1/2 HEISENBERG ANTIFERROMAGNETISM IN CU(C5H5NO)6(CLO4)2 AND CU(C5H5NO)6(BF4)2, RESPECTIVELY
ALGRA, HA
DEJONGH, LJ
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PHYSICA B & C, 1978, 93 (01): : 24 - 34
[29] ASSIGNMENTS OF THE H-1 AND C-13 NMR-SPECTRA OF TRANS-4-HYDROXY-N-9-FLUORENYLMETHOXYCARBONYL-L-PROLINE - USING ONE-DIMENSIONAL AND 2-DIMENSIONAL NMR-SPECTROSCOPY
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MAGNETIC RESONANCE IN CHEMISTRY, 1993, 31 (09) : 876 - 877
[30] C-TERMINAL STRUCTURE AND MOBILITY OF RABBIT SKELETAL-MUSCLE LIGHT-MEROMYOSIN AS STUDIED BY ONE-DIMENSIONAL AND 2-DIMENSIONAL H-1-NMR SPECTROSCOPY AND X-RAY SMALL-ANGLE SCATTERING
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