ONE-DIMENSIONAL AND 2-DIMENSIONAL FOURIER-TRANSFORM SPECTROSCOPY IN THE MICROWAVE AND RADIOFREQUENCY RANGE OF TRIFLUOROMETHANE IN THE VIBRATIONAL-STATE UPSILON-6=1

被引：6
|
作者：
HARDER, H
NICOLAISEN, HW
DREIZLER, H
MADER, H
机构：
[1] Institut für Physikalische Chemie, Abteilung Chemische Physik, Universität Kiel, D-24098 Kiel
来源：
CHEMICAL PHYSICS LETTERS | 1993年 / 214卷 / 3-4期
关键词：
D O I：
10.1016/0009-2614(93)85632-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
For trifluoromethane, CF3H, A1-A2 splittngs with KBAR=\k-l\=3 in the degenerate vibrational state nu6=1 have been determined using two-dimensional radiofrequency-microwave double resonance Fourier transform spectroscopy. The observation of direct l-type resonance transitions with KBAR=3 has been extended to lower J values by means of microwave Fourier transform spectroscopy. The analysis yielded improved values for the rotational constant C6, for the DELTAl= 0, DELTAk = +/- 6 interaction constant w6 and enabled the determination of a J dependence of the DELTAl= +/- 2, DELTAk = -/+ 4 t-type interaction constant.
引用
收藏
页码：265 / 270
页数：6
相关论文
共 39 条
  • [1] 2-DIMENSIONAL FOURIER-TRANSFORM SPECTROSCOPY IN THE MICROWAVE-RADIOFREQUENCY RANGE
    JAGER, W
    HAEKEL, J
    ANDRESEN, U
    MADER, H
    MOLECULAR PHYSICS, 1989, 68 (06) : 1287 - 1309
  • [2] 2-DIMENSIONAL MICROWAVE FOURIER-TRANSFORM SPECTROSCOPY
    VOGELSANGER, B
    BAUDER, A
    JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (07): : 4101 - 4114
  • [3] ROTATIONAL SPECTRUM OF 3-BUTYNENITRILE IN THE MICROWAVE AND RADIOFREQUENCY RANGE USING ONE-DIMENSIONAL AND 2-DIMENSIONAL FOURIER-TRANSFORM TECHNIQUES
    JAGER, W
    KRAUSE, H
    MADER, H
    GERRY, MCL
    JOURNAL OF MOLECULAR SPECTROSCOPY, 1990, 143 (01) : 50 - 60
  • [4] QUADRUPOLE TRANSITIONS IN CF3BR INVESTIGATED BY 2-DIMENSIONAL FOURIER-TRANSFORM SPECTROSCOPY IN THE MICROWAVE-RADIOFREQUENCY RANGE
    HARDER, H
    NICOLAISEN, HW
    DREIZLER, H
    MADER, H
    JOURNAL OF MOLECULAR SPECTROSCOPY, 1993, 160 (01) : 244 - 252
  • [5] STRUCTURAL CONSIDERATION OF A NEW TYPE OF ONE-DIMENSIONAL AND 2-DIMENSIONAL DISCRETE FOURIER-TRANSFORM SYSTEM
    TAKAGI, T
    IEEE TRANSACTIONS ON SYSTEMS MAN AND CYBERNETICS, 1976, 6 (05): : 360 - 366
  • [6] DIRECT ELECTRONIC FOURIER-TRANSFORM DEVICES - EXPERIMENTAL EFFORTS ON ONE-DIMENSIONAL AND 2-DIMENSIONAL SOLID-STATE CAMERAS
    KORNREIC.P
    KOWEL, S
    YANG, NT
    IEEE TRANSACTIONS ON ELECTRON DEVICES, 1973, ED20 (12) : 1176 - 1177
  • [7] SUBMILLIMETREWAVE SPECTROSCOPY OF THE PURE ROTATIONAL TRANSITIONS IN THE UPSILON-6 = 1 VIBRATIONAL-STATE OF (CH3F)-C-12
    PAPOUSEK, D
    PRACNA, P
    TESAR, R
    BELOV, SP
    TRETYAKOV, MY
    VIBRATIONAL SPECTROSCOPY, 1990, 1 (02) : 167 - 171
  • [8] 2-DIMENSIONAL FOURIER-TRANSFORM EPR NUTATION SPECTROSCOPY OF SPIN-CORRELATED RADICAL PAIRS
    HANAISHI, R
    OHBA, Y
    AKIYAMA, K
    YAMAUCHI, S
    IWAIZUMI, M
    JOURNAL OF MAGNETIC RESONANCE SERIES A, 1995, 116 (02) : 196 - 205
  • [9] MULTICHANNEL FOURIER-TRANSFORM SPECTROSCOPY USING 2-DIMENSIONAL DETECTION OF THE INTERFEROGRAM AND ITS APPLICATION TO RAMAN-SPECTROSCOPY
    TAKAHASHI, S
    AHN, JS
    ASAKA, S
    KITAGAWA, T
    APPLIED SPECTROSCOPY, 1993, 47 (07) : 863 - 868
  • [10] APPLICATION OF STEP-SCAN INTERFEROMETRY TO 2-DIMENSIONAL FOURIER-TRANSFORM INFRARED (2D FT-IR) - CORRELATION SPECTROSCOPY
    PALMER, RA
    MANNING, CJ
    CHAO, JL
    NODA, I
    DOWREY, AE
    MARCOTT, C
    APPLIED SPECTROSCOPY, 1991, 45 (01) : 12 - 17
1234