SALTS OF HALOGENOPHOSPHORIC ACIDS .17. PREPARATION AND CRYSTAL-STRUCTURE OF COPPER(II) MONOFLUOROPHOSPHATE DIHYDRATE CUPO3F.2H2O

被引：10
|
作者：
ZEIBIG, M [1 ]
WALLIS, B [1 ]
MOWIUS, F [1 ]
MEISEL, M [1 ]
机构：
[1] ZENT INST ANORGAN CHEM,RUDOWER CHAUSSEE 5,O-1199 BERLIN,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 600卷 / 09期
关键词：
COPPER(II) MONOFLUOROPHOSPHATE DIHYDRATE; SYNTHESIS; CRYSTAL STRUCTURE;
D O I：
10.1002/zaac.19916000132
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Copper(II) monofluorophosphate dihydrate, CuPO3F . 2H2O 1 was obtained by the reaction of aqueous NH4HPO3F and acid (NH4)2PO3F solutions, respectively, using acetone or ethanol as precipitating agents. The thermal dehydration of 1 gives the water-free copper monofluorophosphate CuPO3F (2). 1 crystallizes in the monoclinic space group P2(1)/c with a = 761,44, b = 780,97, c = 921,02 pm, beta = 112,94-degrees and Z = 4.
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页码：231 / 238
页数：8
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