SYNTHESIS AND STRUCTURAL CHARACTERISTICS OF BIS(CITRATE) GERMANATES(IV) (Hbipy)(2) [Ge(HCit)(2)] center dot 2H(2)O AND [CuCl(bipy)(2)](2) [ Ge( HCit) 2] center dot 8H(2)O

被引：5

作者：

Seifullina, Inna ^{[1
]}

Martsinko, Elena ^{[1
]}

Chebanenko, Elena ^{[1
]}

Pirozhok, Olha ^{[1
]}

Dyakonenko, Viktoriya ^{[2
]}

Shishkina, Svitlana ^{[2
,3
]}

机构：

[1] II Mechnikov Odessa Natl Univ, UA-65082 Odessa, Ukraine

[2] Natl Acad Sci Ukraine, SSI Inst Single Crystals, 60 Nauki Ave, UA-61001 Kharkov, Ukraine

[3] Kharkov Natl Univ, 4 Svobody Sq, UA-61077 Kharkov, Ukraine

来源：

CHEMISTRY JOURNAL OF MOLDOVA | 2016年 / 11卷 / 02期

关键词：

germanium(IV) compound; citric acid; 2,2'-bipyridine; copper(II) complex; structure;

D O I：

10.19261/cjm.2016.11(2).11

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystalline compounds (Hbipy)(2) [Ge(HCit)(2)] center dot 2H(2)O (1) and [CuCl(bipy)(2)](2) [Ge(HCit)(2)] center dot 8H(2)O (2) (where H(4)Cit is citric acid, bipy is 2,2'-bipyridine) were obtained for the fi rst time and their structures were determined by the single-crystal X-ray diffraction method. Compounds were characterized by IR spectroscopy, thermogravimetric (TGA) and elemental analyses. Both compounds are formed with complex bis(citrate) germanate anion and protonated 2,2'-bipyridine or [Cu(bipy)(2) Cl](+) as cations in compounds 1 and 2, respectively.

引用

页码：52 / 57

页数：6

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