SYNTHESIS AND STRUCTURAL CHARACTERISTICS OF BIS(CITRATE) GERMANATES(IV) (Hbipy)(2) [Ge(HCit)(2)] center dot 2H(2)O AND [CuCl(bipy)(2)](2) [ Ge( HCit) 2] center dot 8H(2)O

被引：5
|
作者：
Seifullina, Inna [1 ]
Martsinko, Elena [1 ]
Chebanenko, Elena [1 ]
Pirozhok, Olha [1 ]
Dyakonenko, Viktoriya [2 ]
Shishkina, Svitlana [2 ,3 ]
机构：
[1] II Mechnikov Odessa Natl Univ, UA-65082 Odessa, Ukraine
[2] Natl Acad Sci Ukraine, SSI Inst Single Crystals, 60 Nauki Ave, UA-61001 Kharkov, Ukraine
[3] Kharkov Natl Univ, 4 Svobody Sq, UA-61077 Kharkov, Ukraine
来源：
CHEMISTRY JOURNAL OF MOLDOVA | 2016年 / 11卷 / 02期
关键词：
germanium(IV) compound; citric acid; 2,2'-bipyridine; copper(II) complex; structure;
D O I：
10.19261/cjm.2016.11(2).11
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystalline compounds (Hbipy)(2) [Ge(HCit)(2)] center dot 2H(2)O (1) and [CuCl(bipy)(2)](2) [Ge(HCit)(2)] center dot 8H(2)O (2) (where H(4)Cit is citric acid, bipy is 2,2'-bipyridine) were obtained for the fi rst time and their structures were determined by the single-crystal X-ray diffraction method. Compounds were characterized by IR spectroscopy, thermogravimetric (TGA) and elemental analyses. Both compounds are formed with complex bis(citrate) germanate anion and protonated 2,2'-bipyridine or [Cu(bipy)(2) Cl](+) as cations in compounds 1 and 2, respectively.
引用
收藏
页码：52 / 57
页数：6
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