NOVEL ALKYLATION OF AROMATIC NITRILES VIA PHOTOINDUCED ELECTRON-TRANSFER OF GROUP 14 METAL-CARBON SIGMA-DONORS

被引：46

作者：

KYUSHIN, S ^{[1
]}

MASUDA, Y ^{[1
]}

MATSUSHITA, K ^{[1
]}

NAKADAIRA, Y ^{[1
]}

OHASHI, M ^{[1
]}

机构：

[1] UNIV ELECTROCOMMUN,DEPT APPL PHYS & CHEM,CHOFU,TOKYO 182,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 44期

关键词：

D O I：

10.1016/S0040-4039(00)97074-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photo-induced electron transfer reactions of tetraalkylsilanes, -germanes, and -stannanes with aromatic nitriles afforded alkylated products. The mechanism was investigated by use of a radical clock. © 1990.

引用

页码：6395 / 6398

页数：4

共 43 条

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TETRAHEDRON, 1988, 44 (24) : 7335 - 7344
[34] Addition of Group 14 organometallic compounds to C60 via photoinduced electron transfer.: Direct detection of radical ion pair intermediates
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JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 574 (01) : 32 - 39
[35] PHOTOINDUCED COUPLING REACTION OF BENZOTRIAZOLE WITH AROMATIC-HYDROCARBONS SENSITIZED BY 9,10-DICYANOANTHRACENE (DCA) VIA AN ELECTRON-TRANSFER MECHANISM - A SIMPLE SYNTHESIS OF 1-ARYLBENZOTRIAZOLE
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JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (10) : 714 - 715
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (16) : 3655 - 3660
[37] REGIOSELECTIVE CARBON OXYGEN BOND-CLEAVAGE REACTIONS OF AROMATIC ETHERS AND ESTERS WITH POTASSIUM METAL/18-CROWN-6/THF AS THE ELECTRON-TRANSFER REAGENT
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JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (22): : 5230 - 5234
[38] TRANSITION-METAL COMPLEXES WITH SULFUR LIGANDS .67. A NOVEL TYPE OF REACTION - NUCLEOPHILIC ALKYLATION OF THIOLATO LIGANDS BY CARBANIONS VIA INTRAMOLECULAR ELECTRON-TRANSFER - ALKYLATION AND REDUCTION OF [W(S2C6H4)3] BY LITHIUM ALKYLS
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JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (07): : 1733 - 1736
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