NOVEL ALKYLATION OF AROMATIC NITRILES VIA PHOTOINDUCED ELECTRON-TRANSFER OF GROUP 14 METAL-CARBON SIGMA-DONORS

被引：46

作者：

KYUSHIN, S ^{[1
]}

MASUDA, Y ^{[1
]}

MATSUSHITA, K ^{[1
]}

NAKADAIRA, Y ^{[1
]}

OHASHI, M ^{[1
]}

机构：

[1] UNIV ELECTROCOMMUN,DEPT APPL PHYS & CHEM,CHOFU,TOKYO 182,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 44期

关键词：

D O I：

10.1016/S0040-4039(00)97074-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photo-induced electron transfer reactions of tetraalkylsilanes, -germanes, and -stannanes with aromatic nitriles afforded alkylated products. The mechanism was investigated by use of a radical clock. © 1990.

引用

页码：6395 / 6398

页数：4

共 43 条

[21] PHOTOINDUCED ALKYLATION OF 5-MEMBERED HETEROAROMATIC-COMPOUNDS VIA ELECTRON-TRANSFER REACTION - HETERODIMER CATION RADICAL INTERMEDIACY
MIZUNO, K
ISHII, M
OTSUJI, Y
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (18) : 5570 - 5572
[22] PHOTOCHEMICAL CARBON SILICON BOND-FORMING REACTION ON ELECTRON-DEFICIENT ALKENES BY DISILANES AND POLYSILANES VIA PHOTOINDUCED ELECTRON-TRANSFER
MIZUNO, K
NAKANISHI, K
CHOSA, J
OTSUJI, Y
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 473 (1-2) : 35 - 43
[23] PHOTOINDUCED BACK ELECTRON-TRANSFER WITHIN GEMINATE RADICAL ION-PAIRS - OBSERVATION OF THE MARCUS INVERTED REGION IN THE SYSTEM THIONINE WITH SEVERAL AROMATIC DONORS
GRAMPP, G
HETZ, G
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1992, 96 (02): : 198 - 200
[24] Metal Quinolinolate-Fullerene(s) Donor-Acceptor Complexes: Evidence for Organic LED Molecules Acting as Electron Donors in Photoinduced Electron-Transfer Reactions
D'Souza, Francis
Maligaspe, Eranda
Zandler, Melvin E.
Subbaiyan, Navaneetha K.
Ohkubo, Kei
Fukuzumi, Shunichi
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (50) : 16959 - 16967
[25] NO SIGNIFICANT STEREOELECTRONIC EFFECTS OF ISOPROPYL GROUP IN PHOTOADDITION OF ALKYLBENZENE DERIVATIVES WITH 10-METHYLACRIDINIUM ION VIA PHOTOINDUCED ELECTRON-TRANSFER
FUJITA, M
FUKUZUMI, S
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (19) : 1528 - 1529
[26] ENYNE CYCLIZATION VIA PHOTOINDUCED ELECTRON-TRANSFER (PET) GENERATED ELECTROPHILIC SELENIUM SPECIES - A NEW CARBON-CARBON BOND FORMATION STRATEGY
PANDEY, G
SEKHAR, BBVS
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (09) : 780 - 782
[27] METAL HYDRIDE REDUCTIONS VIA SINGLE ELECTRON-TRANSFER .2. EVIDENCE FOR AN ELECTRON-TRANSFER PATHWAY IN THE REACTIONS OF SIMPLE AND COMPLEX METAL-HYDRIDES OF THE MAIN GROUP-METALS WITH POLYNUCLEAR HYDROCARBONS
ASHBY, EC
GOEL, AB
DEPRIEST, RN
PRASAD, HS
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (04) : 973 - 975
[28] GROUP-6 METAL DERIVATIVES OF 2,6-DIPHENYLPHENOXIDE LIGATION - CHELATION VIA METAL-CARBON SIGMA-BONDS AND METAL PI-ARENE INTERACTIONS
KERSCHNER, JL
ROTHWELL, IP
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 : 41 - INOR
[29] A NOVEL (3+2) PHOTOCYCLOADDITION OF (2',2'-DIARYL-VINYLIDENE)CYCLOPROPANES WITH ORGANIC CARBONITRILES VIA PHOTOINDUCED ELECTRON-TRANSFER
MIZUNO, K
NIRE, K
SUGITA, H
OTSUJI, Y
TETRAHEDRON LETTERS, 1993, 34 (41) : 6563 - 6566
[30] EVIDENCE FOR A SINGLE ELECTRON-TRANSFER MECHANISM IN THE REDUCTION OF AROMATIC NITROGEN-HETEROCYCLES WITH MAIN GROUP METAL-HYDRIDES AND DIHYDROPYRIDYL METAL-COMPLEXES
ASHBY, EC
GOEL, AB
TETRAHEDRON LETTERS, 1981, 22 (48) : 4783 - 4786

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