THE CRYSTAL-STRUCTURE OF HYDRONIUM CERIUM-(III) NITRATE HYDRATE, CE(NO3)5(H3O)2-CENTER-DOT-H2O

被引：13
|
作者：
GUILLOU, N
AUFFREDIC, JP
LOUER, M
LOUER, D
机构：
[1] Laboratoire de Cristallochimie (URA CNRS 1495), Universiteé de Rennes, 35042 Rennes Cédex, 1, Avenue du Général Leclerc
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 1993年 / 106卷 / 02期
关键词：
D O I：
10.1006/jssc.1993.1289
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of Ce(NO3)5(H3O)2 · H2O has been determined from three-dimensional single crystal X-ray diffraction data. Crystals are monoclinic, space group P2/c, with a = 21.364(7), b = 7.8990(7), c = 15.133(2) Å β = 91.02(2)°, and Z = 8. Full matrix anisotropic least-squares techniques led to a conventional R factor of 0.049 for 4067 observed reflections. The structure consists of infinite and isolated chains running parallel to [100]. The cerium atoms are twelvefold coordinated by six bidentate nitrate groups. The chains are held together by hydrogen bonds through hydronium ions and water molecules located between the chains. © 1993 Academic Press, Inc.
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页码：295 / 300
页数：6
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