THE CRYSTAL-STRUCTURE OF HYDRONIUM CERIUM-(III) NITRATE HYDRATE, CE(NO3)5(H3O)2-CENTER-DOT-H2O

被引：13
|
作者：
GUILLOU, N
AUFFREDIC, JP
LOUER, M
LOUER, D
机构：
[1] Laboratoire de Cristallochimie (URA CNRS 1495), Universiteé de Rennes, 35042 Rennes Cédex, 1, Avenue du Général Leclerc
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 1993年 / 106卷 / 02期
关键词：
D O I：
10.1006/jssc.1993.1289
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of Ce(NO3)5(H3O)2 · H2O has been determined from three-dimensional single crystal X-ray diffraction data. Crystals are monoclinic, space group P2/c, with a = 21.364(7), b = 7.8990(7), c = 15.133(2) Å β = 91.02(2)°, and Z = 8. Full matrix anisotropic least-squares techniques led to a conventional R factor of 0.049 for 4067 observed reflections. The structure consists of infinite and isolated chains running parallel to [100]. The cerium atoms are twelvefold coordinated by six bidentate nitrate groups. The chains are held together by hydrogen bonds through hydronium ions and water molecules located between the chains. © 1993 Academic Press, Inc.
引用
收藏
页码：295 / 300
页数：6
相关论文
共 50 条
  • [31] Synthesis, Spectroscopic Characterization, and Crystal Structure of the Lanthanide(III) Complex [Ce(hydrazone)2(NO3)(NCS)(H2O)]NO3·2.35H2O
    Damianos G. Paschalidis
    Maria Gdaniec
    Structural Chemistry, 2004, 15 : 605 - 612
  • [32] Synthesis, spectroscopic characterization, and crystal structure of the lanthanide(III) complex [Ce(hydrazone)2(NO3)(NCS)(H2O)]NO3•2.35H2O
    Paschalidis, DG
    Gdaniec, M
    STRUCTURAL CHEMISTRY, 2004, 15 (06) : 605 - 612
  • [33] CRYSTAL-STRUCTURE OF NITRATOTRIAQUO(2,2'-BIPYRIDINE)COPPER(II) NITRATE [CU(NO3)(H2O)3(BIPY)]NO3
    NAKAI, H
    OOI, S
    KUROYA, H
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1977, 50 (02) : 531 - 532
  • [34] Redetermination of [Gd(NO3)(3)(H2O) 4]center dot 2H(2)O
    Taha, Ziyad A.
    Ajlouni, Abdulaziz
    Hijazi, Ahmed K.
    Kuehn, Fritz E.
    Herdtweck, Eberhardt
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : I56 - +
  • [35] Redetermination of [Pr(NO3)(3)(H2O)(4)]center dot 2H(2)O
    Decadt, Roel
    Van Der Voort, Pascal
    Van Driessche, Isabel
    Van Deun, Rik
    Van Hecke, Kristof
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : I59 - +
  • [36] CRYSTAL-STRUCTURE OF HYDRONIUM [(S,S)-N,N'-ETHYLENEDIAMINEDISUCCININATO]COBALTATE(III) HEMIHYDRATE, [H3O][CO(C10H12N2O8)](H2O)0.5
    HORN, E
    SNOW, MR
    TIEKINK, ERT
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1993, 205 : 140 - 142
  • [37] SYNTHESIS AND CRYSTAL-STRUCTURE OF NA2[ND(NO3)5].H2O
    VIGDORCHIK, AG
    MALINOVSKII, YA
    ANDRIANOV, VI
    DRYUCHKO, AG
    INORGANIC MATERIALS, 1990, 26 (11) : 2021 - 2025
  • [38] SYNTHESIS AND CRYSTAL-STRUCTURE OF CESIUM-DYSPROSIUM NITRATE CS[DY(NO3)4(H2O)2].H2O
    VIGDORCHIK, AG
    MALINOVSKY, YA
    DRYUCHKO, AG
    KRISTALLOGRAFIYA, 1989, 34 (06): : 1396 - 1399
  • [39] THE CRYSTAL-STRUCTURE OF THE SODIUM OXOHYDROXOALUMINATE HYDRATE NA-2[AL2O3(OH)(2)]CENTER-DOT-1.5H(2)O
    WEINBERGER, M
    SCHNEIDER, M
    MULLER, D
    GESSNER, W
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (04): : 679 - 684
  • [40] New oxonium bromochalcogenates(IV) - Synthesis, structure, and properties of [H3O][TeBr5]center dot 3 C4H8O2 and [H3O](2)[SeBr6]
    Reich, O
    Hasche, S
    Buscher, K
    Beckmann, I
    Krebs, B
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1996, 622 (06): : 1011 - 1018
12345