THE INTERACTION OF COORDINATIONALLY UNSATURATED 2,9-DIMETHYLPHENANTHROLINE COBALT COMPLEX WITH ADENINE-NUCLEOTIDES

被引：2
|
作者：
KISELEVA, LL
NOVODAROVA, GN
MIRONOV, EA
KRAINOVA, NY
VOLPIN, ME
机构：
[1] A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 117813
来源：
RUSSIAN CHEMICAL BULLETIN | 1994年 / 43卷 / 04期
关键词：
2,9-DIMETHYLPHENANTHROLINE; COBALT COMPLEX; MITOCHONDRIA;
D O I：
10.1007/BF00699850
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The study of complex formation between adenosine triphosphate (ATP) or adenosine diphosphate (ADP) and coordinationally unsaturated cobalt complex with 2,9-dimethyl-o-phenanthroline (L) showed the possibility of formation of relatively stable mixed ligand complex CoL.ATP (log beta = 4.45). The latter may be formed under the oxidative phosphorylation conditions in mitochondria. The presence of ATP in the complex provides the specific inhibition of the ATPase active center.
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页码：696 / 701
页数：6
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