THE INTERACTION OF COORDINATIONALLY UNSATURATED 2,9-DIMETHYLPHENANTHROLINE COBALT COMPLEX WITH ADENINE-NUCLEOTIDES

被引：2

作者：

KISELEVA, LL

NOVODAROVA, GN

MIRONOV, EA

KRAINOVA, NY

VOLPIN, ME

机构：

[1] A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 117813

来源：

RUSSIAN CHEMICAL BULLETIN | 1994年 / 43卷 / 04期

关键词：

2,9-DIMETHYLPHENANTHROLINE; COBALT COMPLEX; MITOCHONDRIA;

D O I：

10.1007/BF00699850

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The study of complex formation between adenosine triphosphate (ATP) or adenosine diphosphate (ADP) and coordinationally unsaturated cobalt complex with 2,9-dimethyl-o-phenanthroline (L) showed the possibility of formation of relatively stable mixed ligand complex CoL.ATP (log beta = 4.45). The latter may be formed under the oxidative phosphorylation conditions in mitochondria. The presence of ATP in the complex provides the specific inhibition of the ATPase active center.

引用

页码：696 / 701

页数：6

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