THE ELECTROCHEMISTRY OF MAGNELI PHASE TITANIUM-OXIDE CERAMIC ELECTRODES .1. THE DEPOSITION AND PROPERTIES OF METAL COATINGS

被引：85
|
作者：
GRAVES, JE
PLETCHER, D
CLARKE, RL
WALSH, FC
机构：
[1] DEXTRA ASSOCIATES,ORINDA,CA
[2] PORTSMOUTH POLYTECH,DEPT CHEM,PORTSMOUTH PO1 2DT,ENGLAND
来源：
JOURNAL OF APPLIED ELECTROCHEMISTRY | 1991年 / 21卷 / 10期
关键词：
D O I：
10.1007/BF01042450
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The electrodeposition of copper, gold, nickel, palladium and platinum onto Ebonex(R) ceramic cathodes has been studied. It is demonstrated that good quality deposits may be obtained and that the kinetics of the deposition and dissolution of metals are similar at Ebonex(R) to other common substrates (for example, Pt, C). In addition, the kinetics of some simple redox couples at coated and bare Ebonex(R) ceramic electrodes are compared; it is confirmed that such electron transfer reactions are very slow on the bare Ebonex(R) ceramic but when the surface is coated with a metal, the kinetics are similar to those on the bulk metal.
引用
收藏
页码：848 / 857
页数：10
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