PALLADIUM CATALYZED STEREOSELECTIVE HYDRODEHALOGENATION OF ALKENYL HALIDES WITH TRIBUTYLTIN HYDRIDE

被引：19
|
作者：
TANIGUCHI, M [1 ]
TAKEYAMA, Y [1 ]
FUGAMI, K [1 ]
OSHIMA, K [1 ]
UTIMOTO, K [1 ]
机构：
[1] KYOTO UNIV, FAC ENGN, DEPT IND CHEM, SAKYO KU, KYOTO 606, JAPAN
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 08期
关键词：
D O I：
10.1246/bcsj.64.2593
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reduction of alkenyl halides with tributyltin hydride in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium has been studied. Alkenyl iodides reacted easily with tributyltin hydride at 25-degrees-C to give the corresponding hydrocarbons stereoselectively. However, the reaction of alkenyl bromides were sluggish at 25-degrees-C and needed heating at 75-degrees-C to complete.
引用
收藏
页码：2593 / 2595
页数：3
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