PALLADIUM CATALYZED STEREOSELECTIVE HYDRODEHALOGENATION OF ALKENYL HALIDES WITH TRIBUTYLTIN HYDRIDE

被引：19

作者：

TANIGUCHI, M ^{[1
]}

TAKEYAMA, Y ^{[1
]}

FUGAMI, K ^{[1
]}

OSHIMA, K ^{[1
]}

UTIMOTO, K ^{[1
]}

机构：

[1] KYOTO UNIV, FAC ENGN, DEPT IND CHEM, SAKYO KU, KYOTO 606, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 08期

关键词：

D O I：

10.1246/bcsj.64.2593

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reduction of alkenyl halides with tributyltin hydride in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium has been studied. Alkenyl iodides reacted easily with tributyltin hydride at 25-degrees-C to give the corresponding hydrocarbons stereoselectively. However, the reaction of alkenyl bromides were sluggish at 25-degrees-C and needed heating at 75-degrees-C to complete.

引用

页码：2593 / 2595

页数：3

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