SYNTHESIS OF N-[1-(TRIALKYLSTANNYL)ALKYL]AMIDES AND AMINES BY THE DISPLACEMENT OF BENZOTRIAZOLES WITH TRIALKYLSTANNYLLITHIUMS

被引：0
|
作者：
PEARSON, WH
STEVENS, EP
机构：
来源：
SYNTHESIS-STUTTGART | 1994年 / 09期
关键词：
BENZOTRIAZOLE; TRIALKYLSTANNYLLITHIUM; SUBSTITUTION; ALPHA-AMINOORGANOSTANNANE; ALPHA-AMINOORGANOLITHIUM;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Condensation of benzotriazole, an aldehyde, and either an amine or amide using the method of Katritzky gave N-[1-benzotriazol-1-yl)alkyl]amides and -amines, which were treated with tributyl,stannyllithium or trimethylstannyllithium to afford N-[1-(trialkyl-stannyl)alkyl]amides and -amines, respectively. These compounds are important precursors of nitrogen-substituted organolithium reagents.
引用
收藏
页码：904 / 906
页数：3
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