SYNTHESIS OF N-[1-(TRIALKYLSTANNYL)ALKYL]AMIDES AND AMINES BY THE DISPLACEMENT OF BENZOTRIAZOLES WITH TRIALKYLSTANNYLLITHIUMS

被引：0
|
作者：
PEARSON, WH
STEVENS, EP
机构：
来源：
SYNTHESIS-STUTTGART | 1994年 / 09期
关键词：
BENZOTRIAZOLE; TRIALKYLSTANNYLLITHIUM; SUBSTITUTION; ALPHA-AMINOORGANOSTANNANE; ALPHA-AMINOORGANOLITHIUM;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Condensation of benzotriazole, an aldehyde, and either an amine or amide using the method of Katritzky gave N-[1-benzotriazol-1-yl)alkyl]amides and -amines, which were treated with tributyl,stannyllithium or trimethylstannyllithium to afford N-[1-(trialkyl-stannyl)alkyl]amides and -amines, respectively. These compounds are important precursors of nitrogen-substituted organolithium reagents.
引用
收藏
页码：904 / 906
页数：3
相关论文
共 50 条
  • [31] N-[1-(BENZOTRIAZOL-1-YL)ALKYL]AMIDES, VERSATILE AMIDOALKYLATION REAGENTS .3. SYNTHESES OF OPEN-CHAIN N-PROTECTED-HEMITHIOAMINALS
    KATRITZKY, AR
    TAKAHASHI, I
    FAN, WQ
    PERNAK, J
    SYNTHESIS-STUTTGART, 1991, (12): : 1147 - 1150
  • [32] THROMBOXANE SYNTHETASE INHIBITORS AND ANTIHYPERTENSIVE AGENTS .1. N-[(1H-IMIDAZOL-1-YL)ALKYL]ARYL AMIDES AND N-[(1H-1,2,4-TRIAZOL-1-YL)ALKYL]ARYL AMIDES
    WRIGHT, WB
    PRESS, JB
    CHAN, PS
    MARSICO, JW
    HAUG, MF
    LUCAS, J
    TAUBER, J
    TOMCUFCIK, AS
    JOURNAL OF MEDICINAL CHEMISTRY, 1986, 29 (04) : 523 - 530
  • [33] Synthesis of vinylogous β-amino esters from N-(N,N-dialkylaminoalkyl)benzotriazoles
    Aurrecoechea, JM
    Fernández, A
    Gorgojo, JM
    Suero, R
    SYNTHETIC COMMUNICATIONS, 2003, 33 (05) : 693 - 702
  • [34] Reactions of New N-(2,2-Dichloro-1-cyanoethenyl)amides with Aliphatic Amines
    O. V. Shablykin
    S. A. Chumachenko
    V. S. Brovarets
    Russian Journal of General Chemistry, 2021, 91 : 1607 - 1612
  • [35] METAL DERIVATIVES OF AMIDOXIMES - SYNTHESIS OF O-(TRIMETHYLSILYL)-N-(TRIALKYLSTANNYL)AMIDOXIMES
    GOEL, AB
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1977, 7 (05): : 445 - 454
  • [36] Reactions of New N-(2,2-Dichloro-1-cyanoethenyl)amides with Aliphatic Amines
    Shablykin, O. V.
    Chumachenko, S. A.
    Brovarets, V. S.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2021, 91 (09) : 1607 - 1612
  • [37] SYNTHESIS OF N-FORMYLGLYCINE ALKYL(BENZYL)AMIDES
    KORSUNSKII, VS
    KOCHERGIN, PM
    SHLIKHUNOVA, VS
    ZHURNAL ORGANICHESKOI KHIMII, 1990, 26 (01): : 82 - 84
  • [38] Synthesis of 1,3-diarylacetones from N-(arylacetyl)benzotriazoles via arylketene intermediates
    Katritzky, AR
    Soleiman, M
    Yang, BZ
    HETEROATOM CHEMISTRY, 1996, 7 (05) : 365 - 367
  • [39] SYNTHESIS AND SPECTROSCOPIC PROPERTIES OF 1-(ARYLTHIOALKYL)BENZOTRIAZOLES AND VINYL SULFIDES
    AFRIDI, AS
    JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 1992, 14 (04): : 270 - 274
  • [40] NEW SYNTHESIS OF DIARYLALKYNES FROM 1-(ARYLMETHYL)BENZOTRIAZOLES AND ARYLIDENEAMINES
    KATRITZKY, AR
    GORDEEV, MF
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1992, (11): : 1295 - 1298
12345