SYNTHESIS OF N-[1-(TRIALKYLSTANNYL)ALKYL]AMIDES AND AMINES BY THE DISPLACEMENT OF BENZOTRIAZOLES WITH TRIALKYLSTANNYLLITHIUMS

被引：0
|
作者：
PEARSON, WH
STEVENS, EP
机构：
来源：
SYNTHESIS-STUTTGART | 1994年 / 09期
关键词：
BENZOTRIAZOLE; TRIALKYLSTANNYLLITHIUM; SUBSTITUTION; ALPHA-AMINOORGANOSTANNANE; ALPHA-AMINOORGANOLITHIUM;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Condensation of benzotriazole, an aldehyde, and either an amine or amide using the method of Katritzky gave N-[1-benzotriazol-1-yl)alkyl]amides and -amines, which were treated with tributyl,stannyllithium or trimethylstannyllithium to afford N-[1-(trialkyl-stannyl)alkyl]amides and -amines, respectively. These compounds are important precursors of nitrogen-substituted organolithium reagents.
引用
收藏
页码：904 / 906
页数：3
相关论文
共 50 条
  • [1] SYNTHESIS OF N-[1-(IMIDAZOL-1-YL)ALKYL]AMIDES
    PERNAK, J
    MROWCZYNSKI, B
    WEGLEWSKI, J
    SYNTHESIS-STUTTGART, 1994, (12): : 1415 - 1417
  • [2] SYNTHESIS OF N-[1-(ACYLOXY)ALKYL]-N'-ARYLCARBODIIMIDES
    VOVK, MV
    DOROKHOV, VI
    MOMOT, VV
    SAMARAI, LI
    ZHURNAL ORGANICHESKOI KHIMII, 1986, 22 (05): : 1099 - 1100
  • [3] ISOMERIZATION OF N-[ALPHA-(ALKYLTHIO)ALKYL]BENZOTRIAZOLES AND N-[ALPHA-(ARYLTHIO)ALKYL]BENZOTRIAZOLES
    KATRITZKY, AR
    KUZMIERKIEWICZ, W
    PERUMAL, S
    HELVETICA CHIMICA ACTA, 1991, 74 (08) : 1936 - 1940
  • [4] The Mitsunobu reaction: An alternative synthesis of 1-(primary alkyl)benzotriazoles
    Katritzky, AR
    Oniciu, DC
    Ghiviriga, I
    SYNTHETIC COMMUNICATIONS, 1997, 27 (09) : 1613 - 1621
  • [5] SYNTHESIS AND PROPERTIES OF N-[1-(ARYLCARBONYLOXY)ALKYL]PYRIDINIUM SALTS
    ANDERS, E
    GASSNER, T
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1982, 21 (04): : 289 - 290
  • [6] N-[1-(BENZOTRIAZOL-1-YL)ALKYL]AMIDES, VERSATILE AMIDOALKYLATION REAGENTS .5. A GENERAL AND CONVENIENT ROUTE TO N-(ALPHA-ALKOXYALKYL)AMIDES
    KATRITZKY, AR
    FAN, WQ
    BLACK, M
    PERNAK, J
    JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (02): : 547 - 549
  • [7] A CONVENIENT SYNTHESIS OF N-(ALPHA-ALKOXYALKYL)AMINES AND N-[ALPHA-(ALKYLTHIO)ALKYL]AMINES
    KATRITZKY, AR
    FAN, WQ
    LONG, QH
    SYNTHESIS-STUTTGART, 1993, (02): : 229 - 232
  • [8] N-[1-(Benzotriazol-1-yl)alkyl]amides from N-acyl-α-amino acids or N-alkylamides
    Adamek, Jakub
    Mazurkiewicz, Roman
    Pazdzierniok-Holewa, Agnieszka
    Kuznik, Anna
    Grymel, Miroslawa
    Zielinska, Katarzyna
    Simka, Wojciech
    TETRAHEDRON, 2014, 70 (35) : 5725 - 5729
  • [9] ADDITION OF NUCLEOPHILIC REAGENTS TO 1-(DIALKOXYPHOSPININYL)ALKYL METHACRYLATES AND N-(1-(DIALKOXYPHOSPHINOTHIOYL)ALKYL]METHACRYLAMIDES
    PUDOVIK, AN
    SAVELEVA, EI
    LAZAREVA, LM
    JOURNAL OF GENERAL CHEMISTRY USSR, 1967, 37 (10): : 2147 - &
  • [10] Hydrazines in the Synthesis of Cytotoxic N-Aryl(alkyl)-N-(hexaoxazadispiroalkyl)amines
    N. N. Makhmudiyarova
    I. R. Ishmukhametova
    L. U. Dzhemileva
    V. A. D’yakonov
    A. G. Ibragimov
    U. M. Dzhemilev
    Russian Journal of Organic Chemistry, 2020, 56 : 797 - 801
12345