Bis[mu-3,5-bis(pyridin-2-yl)-1H-pyrazole]-bis[dibromidoiron(III)]

被引：1

作者：

Katsuta, Nagisa ^{[1
]}

Mishima, Akio ^{[1
]}

Fuyuhiro, Akira ^{[2
]}

Hayami, Shinya ^{[3
]}

Kawata, Satoshi ^{[1
]}

机构：

[1] Fukuoka Univ, Fac Sci, Dept Chem, Jonan Ku, Fukuoka 8140180, Japan

[2] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan

[3] Kumamoto Univ, Grad Sch Sci & Technol, Dept Chem, Kumamoto 8608555, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷

关键词：

D O I：

10.1107/S1600536813026573

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title dinuclear complex, [Fe2Br4(C13H9N4) 2], which lies on an inversion center, features two approximately planar bis(pyridin-2-yl) pyrazole (bpypz(-)) ligands [maximum deviation = 0.082 (3) angstrom] and four bromide ions. Each Fe-III ion is octahedrally coordinated by four N atoms of two bpypz(-) ligands and two Br ions. pi-pi stacking interactions [centroid-centroid distances = 3.7004 (17)-4.0123 (18) angstrom] are observed between pyridyl and pyrazole rings, and between pyridyl and pyridyl rings of adjacent complex molecules.

引用

页码：M574 / +

页数：9

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