Bis[mu-3,5-bis(pyridin-2-yl)-1H-pyrazole]-bis[dibromidoiron(III)]

被引：1
|
作者：
Katsuta, Nagisa [1 ]
Mishima, Akio [1 ]
Fuyuhiro, Akira [2 ]
Hayami, Shinya [3 ]
Kawata, Satoshi [1 ]
机构：
[1] Fukuoka Univ, Fac Sci, Dept Chem, Jonan Ku, Fukuoka 8140180, Japan
[2] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan
[3] Kumamoto Univ, Grad Sch Sci & Technol, Dept Chem, Kumamoto 8608555, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词：
D O I：
10.1107/S1600536813026573
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title dinuclear complex, [Fe2Br4(C13H9N4) 2], which lies on an inversion center, features two approximately planar bis(pyridin-2-yl) pyrazole (bpypz(-)) ligands [maximum deviation = 0.082 (3) angstrom] and four bromide ions. Each Fe-III ion is octahedrally coordinated by four N atoms of two bpypz(-) ligands and two Br ions. pi-pi stacking interactions [centroid-centroid distances = 3.7004 (17)-4.0123 (18) angstrom] are observed between pyridyl and pyrazole rings, and between pyridyl and pyridyl rings of adjacent complex molecules.
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页码：M574 / +
页数：9
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