SYNTHESIS OF METHANOL FROM CARBON-DIOXIDE AND HYDROGEN ON A MOLTEN RANEY CATALYST

被引:0
|
作者
POPOV, IG
SOBOLEVSKII, VS
RESHETNYAK, LF
GOLOVKOVA, AI
机构
来源
关键词
D O I
暂无
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The effect of the technological parameters on the efficiency of a copper-containing molten Raney catalyst and the quality of the methanol raw material was investigated. The studies were conducted using carbon dioxide and hydrogen as the raw material for production of methanol. It was shown that when the temperature and H-2:CO2 ratio were changed, the efficiency of the catalyst passed through a maximum. Increasing the pressure and gas volume flow rate increased the efficiency of the catalyst. A circulation scheme of production of methanol from carbon dioxide and hydrogen was tested. The curve of the catalyst efficiency and quality of product as a function of the H-2:CO2 ratio was calculated with the test. It was shown that it is necessary to keep the H-2:CO2 ratio in the starting gas close to the stoichiometric ratio for obtaining a high degree of conversion of the starting components into methanol.
引用
收藏
页码:1685 / 1690
页数:6
相关论文
共 50 条
  • [31] Methanol synthesis from carbon dioxide and hydrogen via formic ester
    Sakaiya, Y
    Fan, L
    Fujimoto, K
    SEKIYU GAKKAISHI-JOURNAL OF THE JAPAN PETROLEUM INSTITUTE, 1998, 41 (05): : 354 - 357
  • [32] COENZYMES OF METHANOGENESIS FROM HYDROGEN AND CARBON-DIOXIDE
    KELTJENS, JT
    ANTONIE VAN LEEUWENHOEK JOURNAL OF MICROBIOLOGY, 1984, 50 (04): : 383 - 396
  • [33] Methanol synthesis from carbon dioxide over Cu/Zn/Zr catalyst
    Lachowska, M
    Skrzypek, J
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 215 : U435 - U435
  • [34] COADSORPTION OF METHANOL AND CARBON-DIOXIDE ON ALUMINA
    LAMOTTE, J
    SAUR, O
    LAVALLEY, JC
    BUSCA, G
    ROSSI, PF
    LORENZELLI, V
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 : 3019 - 3023
  • [35] REACTIVITY OF HYDROGEN CHEMOSORBED ON NICKEL-CATALYST RELATIVE TO CARBON-DIOXIDE
    BABENKOVA, LV
    KULEVSKAYA, YG
    ZHURNAL FIZICHESKOI KHIMII, 1991, 65 (09): : 2358 - 2362
  • [36] Effect of CuO/ZnO catalyst preparation condition on alcohol-assisted methanol synthesis from carbon dioxide and hydrogen
    Likhittaphon, S.
    Panyadee, R.
    Fakyam, W.
    Charojrochkul, S.
    Sornchamni, T.
    Laosiripojana, N.
    Assabumrungrat, S.
    Kim-Lohsoontorn, P.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (37) : 20782 - 20791
  • [37] Effect of addition of Ce, Cr or/and Ga to a Cu/Zn/Zr catalyst on the methanol synthesis from carbon dioxide and hydrogen
    Hamryszak, Lukasz
    Madej-Lachowska, Maria
    Grzesik, Mirostaw
    Kocot, Karina
    Ruggiero-Mikolajczyk, Malgorzata
    PRZEMYSL CHEMICZNY, 2019, 98 (01): : 133 - 137
  • [38] CATALYTIC PROPERTIES OF NEW CU BASED CATALYSTS CONTAINING ZR AND OR V FOR METHANOL SYNTHESIS FROM A CARBON-DIOXIDE AND HYDROGEN MIXTURE
    KANOUN, N
    ASTIER, MP
    PAJONK, GM
    CATALYSIS LETTERS, 1992, 15 (03) : 231 - 235
  • [39] Methanol synthesis from carbon dioxide and hydrogen using a ceramic memebrane reactor
    Bongkuk Sea
    Kew-Ho Lee
    Reaction Kinetics and Catalysis Letters, 2003, 80 : 33 - 38
  • [40] METHYL FORMATE SYNTHESIS BY HYDROGENATION OF SUPERCRITICAL CARBON-DIOXIDE IN THE PRESENCE OF METHANOL
    JESSOP, PG
    HSIAO, Y
    IKARIYA, T
    NOYORI, R
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (06) : 707 - 708