EFFICIENT CATALYTIC ADDITION OF AROMATIC CARBON-HYDROGEN BONDS TO OLEFINS

被引：1201
|
作者：
MURAI, S
KAKIUCHI, F
SEKINE, S
TANAKA, Y
KAMATANI, A
SONODA, M
CHATANI, N
机构：
[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita
来源：
NATURE | 1993年 / 366卷 / 6455期
关键词：
D O I：
10.1038/366529a0
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
The selective cleavage of carbon-hydrogen bonds in organic compounds is a critical step in many organic syntheses, and is particularly important in the conversion of hydrocarbons to useful organic compounds. An organometallic ruthenium complex can cleave C-H bonds in a variety of aromatic systems, leading to addition to alkenes by C-C bond formation. The catalyst operates with a degree of efficiency, selectivity and generality that will make it extremely valuable in organic synthesis.
引用
收藏
页码：529 / 531
页数：3
相关论文
共 50 条
  • [31] Regioselective functionalization of unreactive carbon-hydrogen bonds
    Daugulis, Olafs
    Zaitsev, Vladimir G.
    Shabashov, Dmitry
    Pham, Quynh-Nhu
    Lazareva, Anna
    SYNLETT, 2006, (20) : 3382 - 3388
  • [32] ELECTRON DISTRIBUTION OF BONDED HYDROGEN ATOM IN CARBON-HYDROGEN BONDS
    MASON, R
    PHILLIPS, DC
    ROBERTSON, GB
    MOLECULAR PHYSICS, 1965, 9 (03) : 277 - +
  • [33] Rhodium-catalyzed silylation of aromatic carbon-hydrogen bonds in 2-arylpyridines with disilane
    Tobisu, Mamoru
    Ano, Yusuke
    Chatani, Naoto
    CHEMISTRY-AN ASIAN JOURNAL, 2008, 3 (8-9) : 1585 - 1591
  • [34] OXIDATIVE ADDITION OF SOLUBLE IRIDIUM AND RHODIUM COMPLEXES TO CARBON-HYDROGEN BONDS IN METHANE AND HIGHER ALKANES
    JANOWICZ, AH
    PERIANA, RA
    BUCHANAN, JM
    KOVAC, CA
    STRYKER, JM
    WAX, MJ
    BERGMAN, RG
    PURE AND APPLIED CHEMISTRY, 1984, 56 (01) : 13 - 23
  • [35] OXIDATIVE-ADDITION OF TERTIARY PHOSPHINE-RUTHENIUM COMPLEXES TO ALLYLIC CARBON-HYDROGEN BONDS
    SHERMAN, EO
    SCHREINER, PR
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (06) : 223 - 224
  • [36] Palladium-catalyzed fluorination of carbon-hydrogen bonds
    Hull, Kami L.
    Anani, Waseem Q.
    Sanford, Melanie S.
    Journal of the American Chemical Society, 2006, 128 (22): : 7134 - 7135
  • [37] The activation of specific bonds in complex molecules at catalytic surfaces II The carbon-hydrogen and carbon-carbon bonds in ethane and ethane-d
    Morikawa, K
    Benedict, WS
    Taylor, HS
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1936, 58 : 1795 - 1800
  • [38] DIHALOCARBENE INSERTIONS INTO CARBON-HYDROGEN BONDS OF HYDROCARBONS AND ETHERS
    GOH, SH
    CHAN, KC
    KAM, TS
    CHONG, HL
    AUSTRALIAN JOURNAL OF CHEMISTRY, 1975, 28 (02) : 381 - 384
  • [39] Palladium-catalyzed fluorination of carbon-hydrogen bonds
    Hull, Kami L.
    Anani, Waseem Q.
    Sanford, Melanie S.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (22) : 7134 - 7135
  • [40] HOMOGENEOUS CATALYTIC ACTIVATION OF CARBON-HYDROGEN BONDS - HYDROGEN-DEUTERIUM EXCHANGE IN SATURATED CARBOXYLIC-ACIDS
    COLFER, PA
    FOGLIA, TA
    PFEFFER, PE
    JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (14): : 2573 - 2575
12345