EFFICIENT CATALYTIC ADDITION OF AROMATIC CARBON-HYDROGEN BONDS TO OLEFINS

被引：1201
|
作者：
MURAI, S
KAKIUCHI, F
SEKINE, S
TANAKA, Y
KAMATANI, A
SONODA, M
CHATANI, N
机构：
[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita
来源：
NATURE | 1993年 / 366卷 / 6455期
关键词：
D O I：
10.1038/366529a0
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
The selective cleavage of carbon-hydrogen bonds in organic compounds is a critical step in many organic syntheses, and is particularly important in the conversion of hydrocarbons to useful organic compounds. An organometallic ruthenium complex can cleave C-H bonds in a variety of aromatic systems, leading to addition to alkenes by C-C bond formation. The catalyst operates with a degree of efficiency, selectivity and generality that will make it extremely valuable in organic synthesis.
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页码：529 / 531
页数：3
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