Mutual isomerization of eta(1)-allenyl and eta(1)-propargyl complexes of platinum via a five-coordinate eta(3)-allenyl/propargyl intermediate

被引：34

作者：

Ogoshi, S

Fukunishi, Y

Tsutsumi, K

Kurosawa, H

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 24期

关键词：

D O I：

10.1039/C39950002485

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reversible spontaneous isomerization between eta(1)-allenyl and eta(1)-propargylplatinum complexes is reported, which is suggested to proceed via pseudorotation of a five-coordinate eta(3)-allenyl/propargyl intermediate.

引用

页码：2485 / 2486

页数：2

共 50 条

[31] Tungsten eta(1)-five-membered oxygenated heterocycles derived from tungsten eta(1)-propargyl compounds: Systematic syntheses, structural rearrangement, electrophilic alkylations, and oxidative demetalations
Shu, HG
Shiu, LH
Wang, SH
Wang, SL
Lee, GH
Peng, SM
Liu, RS
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (03) : 530 - 540
[32] ETA-3-ETA-1 REVERSIBLE ETA-2-TAUTOMERISM IN CARBONYLIRON COMPLEXES - INFLUENCE OF SUBSTITUENTS
RYBIN, LV
STELZER, NA
GARBUSOVA, IA
LOKSHIN, BV
RYBINSKAYA, MI
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 265 (03) : 295 - 303
[33] ETA-3-ETA-1 REVERSIBLE ETA-2-TAUTOMERISM IN CARBONYLIRON COMPLEXES - THERMODYNAMIC CHARACTERISTICS
RYBINSKAYA, MI
RYBIN, LV
STELZER, NA
GARBUSOVA, IA
LOKSHIN, BV
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 265 (03) : 291 - 294
[34] AN UNUSUAL, SELECTIVE ETA(3)-ETA(1) ALLYL ISOMERIZATION IN A CHIRAL ALLYLIC ALKYLATION CATALYST
BREUTEL, C
PREGOSIN, PS
SALZMANN, R
TOGNI, A
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (09) : 4067 - 4068
[35] Reaction of (eta(1)-allenyl)dicarbonyl(eta(5)-cyclopentadienyl)ruthenium with nonacarbonyldiiron: Synthesis and characterization of iron-ruthenium mixed-metal products
Shuchart, CE
Calligaris, M
Churchill, MR
Faleschini, P
See, RF
Wojcicki, A
INORGANICA CHIMICA ACTA, 1996, 243 (1-2) : 109 - 120
[36] TRANSFORMATION OF ETA-3-ALLYL TO MU-ETA-1,ETA-3-ALLYLIDENE IN CERTAIN RUTHENIUM COMPLEXES
EISENSTADT, A
EFRATY, A
ORGANOMETALLICS, 1982, 1 (08) : 1100 - 1101
[37] MONONUCLEAR TRANSITION-METAL ETA-3-PROPARGLY ALLENYL COMPLEXES - SYNTHESIS, STRUCTURE AND REACTION CHEMISTRY
WOJCICKI, A
NEW JOURNAL OF CHEMISTRY, 1994, 18 (01) : 61 - 68
[38] New reaction pathways for mu-eta(1),eta(2)-allenyl ligands: On-off allenyl coordination and CO insertion into the hydrocarbyl bridge in Ru-2(CO)(6)(mu-PPh(2)){mu-eta(1),eta(2)alpha,beta-C(Ph)=C=CP2}
Blenkiron, P
Corrigan, JF
Taylor, NJ
Carty, AJ
Doherty, S
Elsegood, MRJ
Clegg, W
ORGANOMETALLICS, 1997, 16 (03) : 297 - 300
[39] Preparation of 4-Allenyloxazolines from (Z)-2-En-4-yn-1-ol via Propargyl/Allenyl Isomerization
Hung, Shi-Heng
Wang, Yu-Min
Liu, Yi-Hung
Liu, Shiuh-Tzung
JOURNAL OF ORGANIC CHEMISTRY, 2024, 89 (17): : 12762 - 12768
[40] OCTAFLUOROCYCLOOCTATETRAENE TRANSITION-METAL CHEMISTRY - 1,2-ETA AND 1,2,3,6-ETA COMPLEXES OF IRON AND PLATINUM
BAREFOOT, AC
CORCORAN, EW
HUGHES, RP
LEMAL, DM
SAUNDERS, WD
LAIRD, BB
DAVIS, RE
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (04) : 970 - 972

← 1 2 3 4 5 →