Mutual isomerization of eta(1)-allenyl and eta(1)-propargyl complexes of platinum via a five-coordinate eta(3)-allenyl/propargyl intermediate

被引：34

作者：

Ogoshi, S

Fukunishi, Y

Tsutsumi, K

Kurosawa, H

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 24期

关键词：

D O I：

10.1039/C39950002485

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reversible spontaneous isomerization between eta(1)-allenyl and eta(1)-propargylplatinum complexes is reported, which is suggested to proceed via pseudorotation of a five-coordinate eta(3)-allenyl/propargyl intermediate.

引用

页码：2485 / 2486

页数：2

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