FACILE SYNTHESES OF ALPHA,ALPHA-DIFLUORO-BETA-KETOPHOSPHONATES

被引：42

作者：

LEQUEUX, TP ^{[1
]}

PERCY, JM ^{[1
]}

机构：

[1] UNIV BIRMINGHAM,SCH CHEM,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 20期

关键词：

D O I：

10.1039/c39950002111

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cerium-mediated reaction between lithio (diethyldifluoromethyl)-phosphonate 2 proceeds smoothly to afford good yields of ketophosphonates; the reaction with DMF led to the formation of the corresponding aldehyde which was isolated as a hydrate with interesting and useful properties.

引用

页码：2111 / 2112

页数：2

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