FACILE SYNTHESES OF ALPHA,ALPHA-DIFLUORO-BETA-KETOPHOSPHONATES

被引：42
|
作者：
LEQUEUX, TP [1 ]
PERCY, JM [1 ]
机构：
[1] UNIV BIRMINGHAM,SCH CHEM,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 20期
关键词：
D O I：
10.1039/c39950002111
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The cerium-mediated reaction between lithio (diethyldifluoromethyl)-phosphonate 2 proceeds smoothly to afford good yields of ketophosphonates; the reaction with DMF led to the formation of the corresponding aldehyde which was isolated as a hydrate with interesting and useful properties.
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页码：2111 / 2112
页数：2
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