SYNTHESIS AND STRUCTURE OF THE 1ST PHOSPHINE OXIDE COMPLEX OF COPPER(I) - EVIDENCE FOR A MARKED BORDERLINE CHARACTER OF THE METAL CENTER

被引：59
|
作者：
PILLONI, G
CORAIN, B
DEGANO, M
LONGATO, B
ZANOTTI, G
机构：
[1] CNR,CTR STUDIO STABIL & REATTIV COMPOSTI COORDINAZ,I-35131 PADUA,ITALY
[2] CNR,CTR STUDIO BIOPOLIMERI,I-35131 PADUA,ITALY
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 11期
关键词：
D O I：
10.1039/dt9930001777
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The remarkable stability of [Cu(dppf)(odppf)]BF4 [dppf = 1,1'-bis(diphenylphosphino)ferrocene, odppf = 1,1'-bis(oxodiphenylphosphoranyl)ferrocene], characterized in the solid state by X-ray analysis and in solution by P-31 NMR spectroscopy, reveals a marked borderline character of copper(I).
引用
收藏
页码：1777 / 1778
页数：2
相关论文
共 50 条
  • [41] URANIUM ALKOXIDE CHEMISTRY .1. SYNTHESIS AND THE NOVEL DIMERIC STRUCTURE OF THE 1ST HOMOLEPTIC URANIUM(III) ARYLOXIDE COMPLEX
    VANDERSLUYS, WG
    BURNS, CJ
    HUFFMAN, JC
    SATTELBERGER, AP
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (17) : 5924 - 5925
  • [42] SYNTHESIS OF THE 1ST MONOPHOSPHACYCLOBUTADIENE-COBALT(I) COMPLEX BY CODIMERIGATION OF T-BUTYLPHOSPHAACETYLENE WITH BIS(TRIMETHYLSILYL)ACETYLENE
    BINGER, P
    MILCZAREK, R
    MYNOTT, R
    REGITZ, M
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 323 (03) : C35 - C38
  • [43] SYNTHESIS AND 1ST STRUCTURAL CHARACTERIZATION OF A C-3 BOUND ETA-1-PENTADIENYL TRANSITION-METAL COMPLEX
    EARL, PL
    MOORE, DA
    BLEEKE, JR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1989, 197 : 457 - INOR
  • [44] TRANSITION-METAL METHYLENE COMPLEXES .27. SYNTHESIS OF THE 1ST HEAVY-METAL SUBSTITUTED MU-METHYLENE COMPLEX
    HERRMANN, WA
    HUGGINS, JM
    CHEMISCHE BERICHTE-RECUEIL, 1982, 115 (01): : 396 - 398
  • [45] THE 1ST ET SALT WITH A METAL-COMPLEX ANION CONTAINING A SELENOCYANATE LIGAND, (ET)2TLHG(SECN)4 - SYNTHESIS, STRUCTURE AND PROPERTIES
    BURAVOV, LI
    KUSHCH, ND
    LAUKHIN, VN
    KHOMENKO, AG
    YAGUBSKII, EB
    KARTSOVNIK, MV
    KOVALEV, AE
    ROZENBERG, LP
    SHIBAEVA, RP
    TANATAR, MA
    YEFANOV, VS
    DYAKIN, VV
    BONDARENKO, VA
    JOURNAL DE PHYSIQUE I, 1994, 4 (03): : 441 - 451
  • [46] COPPER(I)-INDUCED ADDITION OF AMINES TO UNACTIVATED NITRILES - THE 1ST GENERAL ONE-STEP SYNTHESIS OF ALKYL AMIDINES
    ROUSSELET, G
    CAPDEVIELLE, P
    MAUMY, M
    TETRAHEDRON LETTERS, 1993, 34 (40) : 6395 - 6398
  • [47] SYNTHESIS, CRYSTAL-STRUCTURE AND REACTIONS OF THE 1ST ETA-4 CHROMIUM(0) VINYL KETENE COMPLEX
    WULFF, WD
    ANDERSON, BA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 199 : 215 - INOR
  • [48] SYNTHESIS AND CRYSTAL-STRUCTURE OF THE 1ST BASE-FREE DIARYLGERMYLENE TRANSITION-METAL MONONUCLEAR COMPLEXES
    TOKITOH, N
    MANMARU, K
    OKAZAKI, R
    ORGANOMETALLICS, 1994, 13 (01) : 167 - 171
  • [49] SELECTIVE H-D EXCHANGE IN ALKYLSILANES CATALYZED BY OSMIUM PHOSPHINE COMPLEXES - THE 1ST EVIDENCE FOR BETA-HYDROGEN ELIMINATION FROM A METAL SILYL
    BERRY, DH
    PROCOPIO, LJ
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (11) : 4099 - 4100
  • [50] CRYSTAL-STRUCTURE OF A TETRANUCLEAR COPPER(II)-INOSINE MONOPHOSPHATE-ORTHO-PHENANTHROLINE COMPLEX - 1ST UNAMBIGUOUS EXAMPLE OF O-6 COORDINATION IN A METAL-6-OXOPURINE COMPLEX
    GELLERT, RW
    FISCHER, BE
    BAU, R
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (26) : 7812 - 7815
12345