SYNTHESIS AND STRUCTURE OF THE 1ST PHOSPHINE OXIDE COMPLEX OF COPPER(I) - EVIDENCE FOR A MARKED BORDERLINE CHARACTER OF THE METAL CENTER

被引：59

作者：

PILLONI, G

CORAIN, B

DEGANO, M

LONGATO, B

ZANOTTI, G

机构：

[1] CNR,CTR STUDIO STABIL & REATTIV COMPOSTI COORDINAZ,I-35131 PADUA,ITALY

[2] CNR,CTR STUDIO BIOPOLIMERI,I-35131 PADUA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 11期

关键词：

D O I：

10.1039/dt9930001777

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The remarkable stability of [Cu(dppf)(odppf)]BF4 [dppf = 1,1'-bis(diphenylphosphino)ferrocene, odppf = 1,1'-bis(oxodiphenylphosphoranyl)ferrocene], characterized in the solid state by X-ray analysis and in solution by P-31 NMR spectroscopy, reveals a marked borderline character of copper(I).

引用

页码：1777 / 1778

页数：2

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