SYNTHESIS AND STRUCTURE OF THE 1ST PHOSPHINE OXIDE COMPLEX OF COPPER(I) - EVIDENCE FOR A MARKED BORDERLINE CHARACTER OF THE METAL CENTER

被引：59
|
作者：
PILLONI, G
CORAIN, B
DEGANO, M
LONGATO, B
ZANOTTI, G
机构：
[1] CNR,CTR STUDIO STABIL & REATTIV COMPOSTI COORDINAZ,I-35131 PADUA,ITALY
[2] CNR,CTR STUDIO BIOPOLIMERI,I-35131 PADUA,ITALY
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 11期
关键词：
D O I：
10.1039/dt9930001777
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The remarkable stability of [Cu(dppf)(odppf)]BF4 [dppf = 1,1'-bis(diphenylphosphino)ferrocene, odppf = 1,1'-bis(oxodiphenylphosphoranyl)ferrocene], characterized in the solid state by X-ray analysis and in solution by P-31 NMR spectroscopy, reveals a marked borderline character of copper(I).
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页码：1777 / 1778
页数：2
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