STRUCTURE OF BIS(4-METHYLPYRIDINE-N)COPPER(I) BROMIDE

被引：5
|
作者：
JEDRZEJAS, MJ
MARTUCH, RA
TOWNS, RLR
BAKER, RJ
DURAJ, SA
HEPP, AF
机构：
[1] CLEVELAND STATE UNIV,DEPT CHEM,CLEVELAND,OH 44115
[2] NASA,LEWIS RES CTR,PHOTOVOLTAIC BRANCH,CLEVELAND,OH 44135
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷 / 03期
关键词：
D O I：
10.1107/S0108270192006279
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bromobis(4-methylpyridine)copper(I), [CuBr(C6H7N)2], M(r) = 329.71, triclinic, P1BAR, a = 9.254 (7), b = 9.736 (3), c = 7.955 (3) angstrom, alpha = 102.34 (3), beta = 112.33 (3), gamma = 95.09 (4)-degrees, V = 636.2 (6) angstrom3 , Z = 2, D(m) = 1.8, D(x) = 1.721 g cm-3, lambda(Mo Kalpha) = 0.710326 angstrom, mu = 50.84 cm-1, F(000) = 328, T = 293 K, R = 0.057, wR = 0.088, for 1517 independent observed [I > 3sigma(I)] reflections. An interesting structural feature of this compound is a distance between Cu atoms of 3.101 (2) angstrom within the same unit cell compared to a distance of 6.124 (2) angstrom between Cu atoms of different unit cells.
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页码：536 / 538
页数：3
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