Crystal structure of di-mu-iodido-bis[bis(acetonitrile-kappa N)copper(I)]

被引：4
|
作者：
Barth, Eva Rebecca [1 ]
Golz, Christopher [1 ]
Knorr, Michael [2 ]
Strohmann, Carsten [1 ]
机构：
[1] Tech Univ Dortmund, Fak Chem & Chem Biol, Otto Hahn Str 6, D-44227 Dortmund, Germany
[2] Univ Franche Comte, CNRS, UMR 6213, Inst UTINAM, F-25030 Besancon, France
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; copper(I) iodide complex; dimer;
D O I：
10.1107/S2056989015018149
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Cu2I2(CH3CN)(4)], exhibits a centrosymmetric Cu2I2 core [Cu center dot center dot center dot Cu distance = 2.7482 (11) angstrom], the Cu-I atoms of which are further coordinated by four molecules of acetonitrile. The Cu-I atom has an overall distorted tetrahedral coordination environment evidenced by L-Cu-L angles (L = N or I) ranging from 100.47 (10) to 117.06 (2)degrees. The coordination geometries of the acetonitrile ligands deviate slightly from linearity as shown by Cu-N-C angles of 167.0 (2) and 172.7 (2)degrees. In the crystal, there are no significant hydrogen-bonding interactions present, so the crystal packing seems to be formed predominantly by van der Waals forces.
引用
收藏
页码：M189 / U95
页数：6
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