Crystal structure of di-mu-iodido-bis[bis(acetonitrile-kappa N)copper(I)]

被引：4

作者：

Barth, Eva Rebecca ^{[1
]}

Golz, Christopher ^{[1
]}

Knorr, Michael ^{[2
]}

Strohmann, Carsten ^{[1
]}

机构：

[1] Tech Univ Dortmund, Fak Chem & Chem Biol, Otto Hahn Str 6, D-44227 Dortmund, Germany

[2] Univ Franche Comte, CNRS, UMR 6213, Inst UTINAM, F-25030 Besancon, France

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

关键词：

crystal structure; copper(I) iodide complex; dimer;

D O I：

10.1107/S2056989015018149

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Cu2I2(CH3CN)(4)], exhibits a centrosymmetric Cu2I2 core [Cu center dot center dot center dot Cu distance = 2.7482 (11) angstrom], the Cu-I atoms of which are further coordinated by four molecules of acetonitrile. The Cu-I atom has an overall distorted tetrahedral coordination environment evidenced by L-Cu-L angles (L = N or I) ranging from 100.47 (10) to 117.06 (2)degrees. The coordination geometries of the acetonitrile ligands deviate slightly from linearity as shown by Cu-N-C angles of 167.0 (2) and 172.7 (2)degrees. In the crystal, there are no significant hydrogen-bonding interactions present, so the crystal packing seems to be formed predominantly by van der Waals forces.

引用

页码：M189 / U95

页数：6

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