KINETICS AND ENERGETICS OF THE DISSOCIATION OF H2S MIXED WITH CO2 IN THERMAL PLASMAS

被引:0
|
作者
POTAPKIN, BV
STRELKOVA, MI
FRIDMAN, AA
机构
关键词
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The dissociation of hydrogen sulfide mixed with carbon dioxide in quasiequilibrium thermal plasmas is studied numerically. The major channels for the reaction H2S + CO2 --> products and the mechanisms that describe them are established. The rates of cooling of the dissociation products for which the major products (H2, CO) will be conserved are determined. The range of energy inputs and the conditions for nonadiabatic cooling (quenching) under which sulfur dioxide is not formed are determined. The energy expenditure to obtain synthesis gas is determined as a function of the heating temperature for different rates of cooling.
引用
收藏
页码:50 / 55
页数:6
相关论文
共 50 条
  • [41] CALCULATION OF POTENTIAL SURFACES FOR H2S AND CO2 MOLECULES
    GRIBOV, LA
    KHOVRIN, GV
    OPTIKA I SPEKTROSKOPIYA, 1974, 36 (06): : 1098 - 1102
  • [42] When is CO2 more hazardous than H2S
    Tyndall, K.
    McIntush, K.
    Lundeen, J.
    Fisher, K.
    Beitler, C.
    HYDROCARBON PROCESSING, 2011, 90 (01): : 45 - 48
  • [43] SOLUBILITY OF H2S, CO2 AND THEIR MIXTURES IN AN AMP SOLUTION
    TENG, TT
    MATHER, AE
    CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1989, 67 (05): : 846 - 850
  • [44] Effect of H2S concentration on the corrosion behavior of pipeline steel under the coexistence of H2S and CO2
    Li, Da-peng
    Zhang, Lei
    Yang, Jian-wei
    Lu, Min-xu
    Ding, Jin-hui
    Liu, Ming-liang
    INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS, 2014, 21 (04) : 388 - 394
  • [45] Plasmas for destruction of H2S and mercaptans
    Czernichowski, A
    OIL & GAS SCIENCE AND TECHNOLOGY-REVUE D IFP ENERGIES NOUVELLES, 1999, 54 (03): : 337 - 355
  • [46] Effect of H2S concentration on the corrosion behavior of pipeline steel under the coexistence of H2S and CO2
    Da-peng Li
    Lei Zhang
    Jian-wei Yang
    Min-xu Lu
    Jin-hui Ding
    Ming-liang Liu
    International Journal of Minerals Metallurgy and Materials, 2014, 21 (04) : 388 - 394
  • [47] H2S分压对油管钢CO2/H2S腐蚀的影响
    张清
    李全安
    文九巴
    白真权
    腐蚀科学与防护技术, 2004, (06) : 395 - 397
  • [48] Effect of H2S concentration on the corrosion behavior of pipeline steel under the coexistence of H2S and CO2
    Da-peng Li
    Lei Zhang
    Jian-wei Yang
    Min-xu Lu
    Jin-hui Ding
    Ming-liang Liu
    International Journal of Minerals, Metallurgy, and Materials, 2014, 21 : 388 - 394
  • [49] H2S-CO2 gas separation with ionic liquids on low ratio of H2S/CO2
    Adhi, Tri Partono
    Situmorang, Yohanes Andre
    Winoto, Haryo Pandu
    Ariono, Danu
    Septiana, Diannisa
    Imanuela, Patricia
    Indarto, Antonius
    HELIYON, 2021, 7 (12)
  • [50] Explosion limits of the tenary gas systems H2S/CO2/air and H2S/N2/air
    Pahl, R
    Holtappels, K
    CHEMIE INGENIEUR TECHNIK, 2004, 76 (10) : 1558 - 1561