ON THE DIFFERENCE IN THE RESULTS OF REDUCTIVE DEFLUORINATION OF PENTAFLUOROBENZOIC ACID BY SODIUM AND ZINC IN LIQUID-AMMONIA MEDIUM

被引：13
|
作者：
LAEV, SS
SHTEINGARTS, VD
BILKIS, II
机构：
[1] RUSSIAN ACAD SCI,DIV SIBERIAN,INST ORGAN CHEM,NOVOSIBIRSK 630090,RUSSIA
[2] HEBREW UNIV JERUSALEM,FAC AGR,IL-76100 REHOVOT,ISRAEL
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 26期
关键词：
D O I：
10.1016/0040-4039(95)00827-Y
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Under the reduction of pentafluorobenzoic acid in liquid ammonia by sodium the deep defluorination with removal of three or more fluorine atoms has been observed, whereas with zinc only the product of para-defluorination has been obtained.
引用
收藏
页码：4655 / 4658
页数：4
相关论文
共 50 条
  • [41] REDUCTION OF ALKYL-SUBSTITUTED BUTADIENES BY SODIUM IN LIQUID-AMMONIA
    REEVE, W
    KURODA, DR
    JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (12): : 2305 - 2307
  • [42] PARA-HYDROGEN CONVERSION BY SOLUTIONS OF SODIUM IN LIQUID-AMMONIA
    BOOTLE, GA
    ELEY, DD
    RUDHAM, R
    ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE NEUE FOLGE, 1985, 144 : 47 - 57
  • [43] DEOXYGENATION OF SUGAR TRIFLUOROMETHANESULFONATES BY SODIUM METAL IN LIQUID-AMMONIA AND BY PHOTOLYSIS
    TSUCHIYA, T
    NAKAMURA, F
    UMEZAWA, S
    TETRAHEDRON LETTERS, 1979, (30) : 2805 - 2808
  • [44] REACTION OF SUBSTITUTED BENZALDEHYDES WITH SODIUM HYDROGEN SULFIDE OR SODIUM SULFIDE IN LIQUID-AMMONIA
    TAKIKAWA, Y
    SHIMADA, K
    MINAMI, T
    SATO, R
    TAKIZAWA, S
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (02) : 511 - 514
  • [45] HYDROGEN AND NITROGEN EVOLUTION REACTIONS IN ACID LIQUID-AMMONIA
    TRASATTI, S
    MILES, MH
    YATES, CA
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1974, 121 (12) : 1609 - 1610
  • [46] HYDROGEN AND NITROGEN EVOLUTION REACTIONS IN ACID LIQUID-AMMONIA
    MILES, MH
    YATES, CA
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1974, 121 (02) : 230 - 233
  • [47] Reductive desulfurization of organosulfur compounds with sodium in liquid ammonia
    Yu, ZK
    Verkade, JG
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1998, 133 : 79 - 82
  • [48] REDUCTIVE DEGRADATION OF LIGNINCARBOHYDRATE COMPLEXES BY SODIUM IN LIQUID AMMONIA
    EFENDIEVA, NF
    SHORYGIN.NN
    KRASOVSK.NP
    IZVESTIYA AKADEMII NAUK SSSR-SERIYA KHIMICHESKAYA, 1973, (12): : 2812 - 2815
  • [49] RADIOLYSIS OF LIQUID-AMMONIA IN BASIC MEDIUM .1. INFLUENCE OF PH
    BELLONI, J
    FRADINDE.J
    INTERNATIONAL JOURNAL FOR RADIATION PHYSICS AND CHEMISTRY, 1973, 5 (01): : 23 - 30
  • [50] REDUCTIVE TRANSFORMATIONS .5. ALTERNATIVE ROUTES FOR REDUCTIVE ALKYLATIONS IN LIQUID-AMMONIA AND THEIR SELECTION VIA SPECTROSCOPIC EVIDENCE
    MULLEN, K
    HUBER, W
    NEUMANN, G
    SCHNIEDERS, C
    UNTERBERG, H
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (04) : 801 - 807
12345