ON THE DIFFERENCE IN THE RESULTS OF REDUCTIVE DEFLUORINATION OF PENTAFLUOROBENZOIC ACID BY SODIUM AND ZINC IN LIQUID-AMMONIA MEDIUM

被引:13
|
作者
LAEV, SS
SHTEINGARTS, VD
BILKIS, II
机构
[1] RUSSIAN ACAD SCI,DIV SIBERIAN,INST ORGAN CHEM,NOVOSIBIRSK 630090,RUSSIA
[2] HEBREW UNIV JERUSALEM,FAC AGR,IL-76100 REHOVOT,ISRAEL
关键词
D O I
10.1016/0040-4039(95)00827-Y
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Under the reduction of pentafluorobenzoic acid in liquid ammonia by sodium the deep defluorination with removal of three or more fluorine atoms has been observed, whereas with zinc only the product of para-defluorination has been obtained.
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页码:4655 / 4658
页数:4
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