THE METAL ALKYL BOND-ENERGY OF THE FE(100) HYDROGEN ETHYL SURFACE COMPLEX

被引：19

作者：

BURKE, ML

MADIX, RJ

机构：

[1] STANFORD UNIV,DEPT CHEM & CHEM ENGN,STANFORD,CA 94305

[2] STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1992年 / 114卷 / 08期

关键词：

D O I：

10.1021/ja00034a002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A thermochemical cycle has been constructed for the reactions of ethylene on H-presaturated Fe(100); this cycle has been used to accurately determine Fe-C2H5 and Fe-H surface bond energies of 38 +/- 4 and 59.5 +/- 2 kcal/mol, respectively. The Fe-C2H5 bond energy is considerably smaller than that measured in the gas phase. Both values are similar to those expected for mononuclear transition metal complexes, provided that the complex contains a first or second row transition metal and is not sterically crowded.

引用

页码：2780 / 2783

页数：4

共 50 条

[31] SURFACE SILICON-DEUTERIUM BOND-ENERGY FROM GAS-PHASE EQUILIBRATION
WAMPLER, WR
MYERS, SM
FOLLSTAEDT, DM
PHYSICAL REVIEW B, 1993, 48 (07): : 4492 - 4497
[32] CHEMISORPTION OF NITROUS-OXIDE ON TRANSITION-METAL SURFACES - BOND-ENERGY BOND ORDER MODEL CALCULATION
VETRIVEL, R
GOPALAKRISHNAN, R
VISWANATHAN, B
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1982, 21 (02): : 157 - 158
[33] FE-56 AND CO-59 LEVELS, LOCATED ABOVE NEUTRON BOND-ENERGY
ABRAMOV, AI
KITAEV, VY
YUTKIN, MG
IZVESTIYA AKADEMII NAUK SSSR SERIYA FIZICHESKAYA, 1974, 38 (10): : 2112 - 2118
[34] ON THE CORRELATIONS BETWEEN CATALYTIC ACTIVITY OF METAL-OXIDES IN OXIDATION REACTIONS AND METAL-OXYGEN BOND-ENERGY
CRIADO, JM
AFINIDAD, 1980, 37 (367) : 205 - 208
[35] DEPENDENCE OF CATALYTIC PROPERTIES OF COBALT MOLYBDATE IN PROPYLENE OXIDATION ON SURFACE REDUCTION AND OXYGEN BOND-ENERGY
ANDRUSHKEVICH, TV
BORESKOV, GK
PANKRATIEV, YD
POPOVA, GY
KOZMENKO, ON
KULIEV, AR
REACTION KINETICS AND CATALYSIS LETTERS, 1977, 7 (02): : 187 - 191
[36] BOND-ENERGY OF SURFACE OXYGEN IN OXIDE CATALYSTS, AND THEIR SELECTIVITY IN OXIDATIVE DEHYDROGENATION OF 1-BUTENE
BORESKOV, GK
VENYAMINOV, SA
SAZONOVA, NN
PANKRATEV, YD
PITAEVA, AN
KINETICS AND CATALYSIS, 1975, 16 (06) : 1253 - 1257
[37] AN EXAMINATION OF ALLENS EMPIRICAL BOND-ENERGY SCHEME, AND ITS APPLICATION TO PARAFFINS AND CYCLOALKANES, OLEFINS, ALKYL ALCOHOLS AND BROMIDES, AND AMINES
SKINNER, HA
JOURNAL OF THE CHEMICAL SOCIETY, 1962, (NOV): : 4396 - &
[38] METAL, BOND-ENERGY, AND ANCILLARY LIGAND EFFECTS ON ACTINIDE-CARBON SIGMA-BOND HYDROGENOLYSIS - A KINETIC AND MECHANISTIC STUDY
LIN, ZR
MARKS, TJ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (26) : 7979 - 7985
[39] FIRST TRANSITION METAL-BORYL BOND-ENERGY AND QUANTITATION OF LARGE DIFFERENCES IN SEQUENTIAL BOND-DISSOCIATION ENERGIES OF BORANES
RABLEN, PR
HARTWIG, JF
NOLAN, SP
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (09) : 4121 - 4122
[40] THEORETICAL PREDICTION OF THE STRUCTURE AND THE BOND-ENERGY OF THE GOLD(I) COMPLEX AU(+) (H2O)
HRUSAK, J
SCHRODER, D
SCHWARZ, H
CHEMICAL PHYSICS LETTERS, 1994, 225 (4-6) : 416 - 420

← 1 2 3 4 5 →