THE METAL ALKYL BOND-ENERGY OF THE FE(100) HYDROGEN ETHYL SURFACE COMPLEX

被引：19
|
作者：
BURKE, ML
MADIX, RJ
机构：
[1] STANFORD UNIV,DEPT CHEM & CHEM ENGN,STANFORD,CA 94305
[2] STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1992年 / 114卷 / 08期
关键词：
D O I：
10.1021/ja00034a002
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A thermochemical cycle has been constructed for the reactions of ethylene on H-presaturated Fe(100); this cycle has been used to accurately determine Fe-C2H5 and Fe-H surface bond energies of 38 +/- 4 and 59.5 +/- 2 kcal/mol, respectively. The Fe-C2H5 bond energy is considerably smaller than that measured in the gas phase. Both values are similar to those expected for mononuclear transition metal complexes, provided that the complex contains a first or second row transition metal and is not sterically crowded.
引用
收藏
页码：2780 / 2783
页数：4
相关论文
共 50 条
12345