LIGAND REACTIVITY IN IRON(II) COMPLEXES OF 4'-(4'''-PYRIDYL)-2,2'/6',2''-TERPYRIDINE

被引:165
|
作者
CONSTABLE, EC
THOMPSON, AMWC
机构
关键词
D O I
10.1039/dt9920002947
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The ligand 4'-(4'"-pyridyl)-2,2':6',2"-terpyridine (pyterpy) acts as a tridentate ligand in which the 4-pyridyl ring is not co-ordinated in the complex cation [Fe(pyterpy)2]2+; the non-co-ordinated ring reacts with electrophiles to give species in which the charge perturbations are localised to a '4,4'-bipyridyl' fragment.
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页码:2947 / 2950
页数:4
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